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Enhancement of Eu3+ Red Upconversion in Lu2O3: Yb3+/Eu3+ Powders under the Assistance of Bridging Function Originated from Ho3+ Tridoping
Xiang, G. T.; Y. Ma; W. Liu; J. P. Wang; Z. W. Gu; Y. Jin; S. Jiang; X. B. Luo; L. Li; X. J. Zhou; Y. S. Luo and J. H. Zhang
2017
Source PublicationInorganic Chemistry
Volume56Issue:22
AbstractThe red upconversion (UC) emission of Eu3+ ions in Lu2O3: Yb3+/Eu3+ powders was successfully enhanced by tridoping Ho3+ ions in the matrix, which is due to the bridging function of Ho3+ ions. The experiment data manifest that, in Yb3+/Eu3+/Ho3+ tridoped system, the Ho3+ ions are first populated to the green emitting level F-5(4)/S-5(2) through the energy transfer (ET) processes from the excited Yb3+ ions. Subsequently, the Ho3+ ions at F-5(4)/S-5(2) level can transfer their energy to the Eu3+ ions at the ground state, resulting in the population of Eu3+ D-5(0) level. With the assistance of the bridging function of Ho3+ ion, this ET process is more efficient than the cooperative sensitization process between Yb3+ ion and Eu3+ ion. Compared with Lu2O3: 5 mol % Yb3+/1 mol % Eu3+, the UC intensity of Eu3+ D-5(0) -> F-7(2) transition in Lu2O3: 5 mol % Yb3+/1 mol % Eu3+/0.5 mol % Ho3+ is increased by a factor of 8.
Indexed Bysci ; ei
Language英语
WOS IDWOS:000416297200034
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ciomp.ac.cn/handle/181722/59328
Collection中科院长春光机所知识产出
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GB/T 7714
Xiang, G. T.,Y. Ma,W. Liu,et al. Enhancement of Eu3+ Red Upconversion in Lu2O3: Yb3+/Eu3+ Powders under the Assistance of Bridging Function Originated from Ho3+ Tridoping[J]. Inorganic Chemistry,2017,56(22).
APA Xiang, G. T..,Y. Ma.,W. Liu.,J. P. Wang.,Z. W. Gu.,...&Y. S. Luo and J. H. Zhang.(2017).Enhancement of Eu3+ Red Upconversion in Lu2O3: Yb3+/Eu3+ Powders under the Assistance of Bridging Function Originated from Ho3+ Tridoping.Inorganic Chemistry,56(22).
MLA Xiang, G. T.,et al."Enhancement of Eu3+ Red Upconversion in Lu2O3: Yb3+/Eu3+ Powders under the Assistance of Bridging Function Originated from Ho3+ Tridoping".Inorganic Chemistry 56.22(2017).
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