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Photoluminescence and charge compensation effects in Lu3MgyAl5-x-ySixO12:Ce3+ phosphors for white LEDs
Qiao, J.; L. J. Shen; W. G. Xiao; X. Qiao; Z. Z. Wang; L. L. Gao; B. Li; Y. B. Zhou; X. Zhang and X. Y. Zhang
2017
发表期刊Journal of Alloys and Compounds
卷号695
摘要Phosphors with the nominal composition Lu2.94Ce0.06MgyAl5-x-ySixO12 (x = 0-2, y = 0-2) were synthesized by a conventional solid-state reaction in a reducing atmosphere (CO). The luminescence properties of these phosphors and the effect of charge compensation are discussed in detail. Our results indicate that the substitution of Mg2+ for Al3+ ions at octahedral coordination sites and the substitution of Si4+ for Al3+ ions at tetrahedral coordination sites are co-dependent processes because of charge compensation. Only when co-doping with Mg2+ and Si4+ ions, the incorporation of Mg2+ ions into octahedral coordination sites can be achieved. On incorporation of Mg2+ ions into the phosphor, an obvious red shift in the luminescence was observed. In addition, we analyzed the dependence of luminescence intensity on the absorptivity and the thermal quenching of the Ce3+ ions. The luminescence performances of white LEDs, fabricated by combining a single orange Lu2.94Ce0.06MgyAl5-x-ySixO12 phosphor with blue LED chips, were determined, which demonstrate the potential of this orange phosphor for use in warm white LEDs. (C) 2016 Elsevier B.V. All rights reserved.
收录类别sci ; ei
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/59160
专题中科院长春光机所知识产出
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Qiao, J.,L. J. Shen,W. G. Xiao,et al. Photoluminescence and charge compensation effects in Lu3MgyAl5-x-ySixO12:Ce3+ phosphors for white LEDs[J]. Journal of Alloys and Compounds,2017,695.
APA Qiao, J..,L. J. Shen.,W. G. Xiao.,X. Qiao.,Z. Z. Wang.,...&X. Zhang and X. Y. Zhang.(2017).Photoluminescence and charge compensation effects in Lu3MgyAl5-x-ySixO12:Ce3+ phosphors for white LEDs.Journal of Alloys and Compounds,695.
MLA Qiao, J.,et al."Photoluminescence and charge compensation effects in Lu3MgyAl5-x-ySixO12:Ce3+ phosphors for white LEDs".Journal of Alloys and Compounds 695(2017).
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