Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks

	Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks
	Xiao, L. N.; L. M. Wang; X. N. Shan; H. Y. Guo; L. W. Fu; Y. Y. Hu; X. B. Cui; K. C. Li and J. Q. Xu
	2015
发表期刊	Crystengcomm
卷号	17 期号:6 页码:1336-1347
摘要	Four new organic-inorganic hybrid compounds, namely, [Cu3(4,4'-bpy)3][HSiW12O40]center dot(C3H4N2) (1), [Cu-3(4,4'-bpy)(3)][PMo12O40]center dot(C5H6N2)center dot 0.5H(2)O (2), [Cu-2(4,4'-bpy)(2)][HPMo12O40]center dot(C5H6N2) (3) and [Cu(Phen)(4,4'-bpy)(H2O)](2)[PW12O40]center dot(4,4'-bpy) (4) (C3H4N2 = imidazole, C5H6N2 = 2-aminopyridine, bpy = bipyridine, Phen = 1,10-phenanthroline), have been synthesized and characterized by IR, UV-vis, powder XRD, cyclic voltammetry analysis, photoluminescence analysis, elemental analyses and single crystal X-ray diffraction. The four compounds represent new examples of secondary organic moiety templated frameworks constructed from Keggin polyanions, metal ions and organic ligands. Compounds 1 and 2 present 3-D framework structures; compound 3 exhibits a 1-D ladder-like structure and compound 4 shows a 2-D layered framework structure. It is noted that the packing structures of compounds 1 and 2 are almost identical; however, the crystal space groups and cell parameters of the two are thoroughly different. Such a phenomenon has also been observed between compound 3 and a compound recently reported by us. Compound 4 is the first framework structure constructed from polyoxometalates, metal ions and mixed organic ligands. In addition, all the four frameworks are combined with dissociated organic moieties as templates.
收录类别	SCI
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/55484
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Xiao, L. N.,L. M. Wang,X. N. Shan,et al. Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks[J]. Crystengcomm,2015,17(6):1336-1347.
APA	Xiao, L. N..,L. M. Wang.,X. N. Shan.,H. Y. Guo.,L. W. Fu.,...&K. C. Li and J. Q. Xu.(2015).Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks.Crystengcomm,17(6),1336-1347.
MLA	Xiao, L. N.,et al."Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks".Crystengcomm 17.6(2015):1336-1347.

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