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Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks
Xiao, L. N.; L. M. Wang; X. N. Shan; H. Y. Guo; L. W. Fu; Y. Y. Hu; X. B. Cui; K. C. Li and J. Q. Xu
2015
发表期刊Crystengcomm
卷号17期号:6页码:1336-1347
摘要Four new organic-inorganic hybrid compounds, namely, [Cu3(4,4'-bpy)3][HSiW12O40]center dot(C3H4N2) (1), [Cu-3(4,4'-bpy)(3)][PMo12O40]center dot(C5H6N2)center dot 0.5H(2)O (2), [Cu-2(4,4'-bpy)(2)][HPMo12O40]center dot(C5H6N2) (3) and [Cu(Phen)(4,4'-bpy)(H2O)](2)[PW12O40]center dot(4,4'-bpy) (4) (C3H4N2 = imidazole, C5H6N2 = 2-aminopyridine, bpy = bipyridine, Phen = 1,10-phenanthroline), have been synthesized and characterized by IR, UV-vis, powder XRD, cyclic voltammetry analysis, photoluminescence analysis, elemental analyses and single crystal X-ray diffraction. The four compounds represent new examples of secondary organic moiety templated frameworks constructed from Keggin polyanions, metal ions and organic ligands. Compounds 1 and 2 present 3-D framework structures; compound 3 exhibits a 1-D ladder-like structure and compound 4 shows a 2-D layered framework structure. It is noted that the packing structures of compounds 1 and 2 are almost identical; however, the crystal space groups and cell parameters of the two are thoroughly different. Such a phenomenon has also been observed between compound 3 and a compound recently reported by us. Compound 4 is the first framework structure constructed from polyoxometalates, metal ions and mixed organic ligands. In addition, all the four frameworks are combined with dissociated organic moieties as templates.
收录类别SCI
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/55484
专题中科院长春光机所知识产出
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Xiao, L. N.,L. M. Wang,X. N. Shan,et al. Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks[J]. Crystengcomm,2015,17(6):1336-1347.
APA Xiao, L. N..,L. M. Wang.,X. N. Shan.,H. Y. Guo.,L. W. Fu.,...&K. C. Li and J. Q. Xu.(2015).Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks.Crystengcomm,17(6),1336-1347.
MLA Xiao, L. N.,et al."Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks".Crystengcomm 17.6(2015):1336-1347.
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