Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Bilayer and 3-D open framework: Pillared metal-organic frameworks based on zinc and cadmic (6,3)-layers | |
Wang C. R.; Sun F. X.; Zhang K.; Zheng C. B. | |
2014 | |
发表期刊 | Inorganic Chemistry Communications |
ISSN | ISBN/1387-7003 |
期号 | 48页码:65-68 |
摘要 | The (6,3)-layers of transition metals and 3,5-pyridinecarboxylate (3,5-PDC) containing terminal coordinated molecules offer a great potential for obtained porous frameworks via the "pillaring" approach. In this work, we have successfully obtained two porous frameworks based on the zinc and cadmic (6,3)-layers (compounds 1 and 2, respectively) pillared by 4,4'-pyridine (bipy). Interestingly, different metal centers of Zn(II) and Cd(II) in the (6,3)-layers lead to the pillared frameworks into bilayers with {6(3))(6(6)) topology (compound 3) and 3-D open framework with {6(3)}{6(9).8) hms topology (compound 4), respectively. It is believed that this work deserves further focus to enrich the design strategy of novel porous crystalline metal-organic frameworks (MOFs). (C) 2014 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/43767 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Wang C. R.,Sun F. X.,Zhang K.,et al. Bilayer and 3-D open framework: Pillared metal-organic frameworks based on zinc and cadmic (6,3)-layers[J]. Inorganic Chemistry Communications,2014(48):65-68. |
APA | Wang C. R.,Sun F. X.,Zhang K.,&Zheng C. B..(2014).Bilayer and 3-D open framework: Pillared metal-organic frameworks based on zinc and cadmic (6,3)-layers.Inorganic Chemistry Communications(48),65-68. |
MLA | Wang C. R.,et al."Bilayer and 3-D open framework: Pillared metal-organic frameworks based on zinc and cadmic (6,3)-layers".Inorganic Chemistry Communications .48(2014):65-68. |
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