Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Thermotropic liquid crystals built from organic-inorganic hybrid polyoxometalates and a simple cationic surfactant | |
Jia Y.; Tan H. Q.; Zhang Z. M.; Wang E. B. | |
2013 | |
发表期刊 | Journal of Materials Chemistry C |
ISSN | ISBN/2050-7526 |
卷号 | 1期号:23 |
摘要 | By ion metathesis reactions, the dimethyldioctadecylammonium (DODA(+)) was used as the surfactant to encapsulate organic-inorganic hybrid polyoxometalates (POMs) (NH4)(6){(Mo2O4)-O-V[((Mo2O6)-O-VI)-NH3CH2CH2CH2C(O)(PO3)(2)](2)}center dot 10H(2)O (POM-1) and (NH4)(8){(Mo2O4)-O-V[((Mo2O6)-O-VI)CH3C(O)(PO3)(2)](2)}center dot 14H(2)O (POM-2), resulting in two surfactant-encapsulated clusters (SECs) with characteristic thermotropic liquid-crystalline behavior. The chemical composition of the obtained SECs was determined by IR spectra, elemental analysis, TG analysis and NMR spectra. Also, polarized optical microscopy, differential scanning calorimetry (DSC), variable temperature X-ray diffraction (VT-XRD) and TEM of the samples were also performed, which revealed that both SECs show thermotropic liquid crystal behavior. |
收录类别 | SCI ; EI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/40903 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Jia Y.,Tan H. Q.,Zhang Z. M.,et al. Thermotropic liquid crystals built from organic-inorganic hybrid polyoxometalates and a simple cationic surfactant[J]. Journal of Materials Chemistry C,2013,1(23). |
APA | Jia Y.,Tan H. Q.,Zhang Z. M.,&Wang E. B..(2013).Thermotropic liquid crystals built from organic-inorganic hybrid polyoxometalates and a simple cationic surfactant.Journal of Materials Chemistry C,1(23). |
MLA | Jia Y.,et al."Thermotropic liquid crystals built from organic-inorganic hybrid polyoxometalates and a simple cationic surfactant".Journal of Materials Chemistry C 1.23(2013). |
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