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Controllable synthesis, growth mechanism and optical properties of the ZnSe quantum dots and nanoparticles with different crystalline phases
Feng B.; Yang J.; Cao J.; Yang L.; Gao M.; Wei M.; Liu Y.; Song H.
2013
发表期刊Materials Research Bulletin
ISSNISBN/00255408
卷号48期号:3
摘要ZnSe precursors were prepared by a solvothermal method at 180C without any surface-active agents. ZnSe quantum dots and nanoparticles were obtained by annealing the precursors at 300C for 2 h in argon atmosphere. The ZnSe quantum dots were about 3.5 nm, while the ZnSe nanoparticles were about 21 nm, as observed using TEM. The growth mechanisms for the two samples were discussed; this proved that the high coordination ability of ethylenediamine to zinc played an important role in the final phase of the products. The ZnSe quantum dots with the wurtzite structure exhibited a strong near band-edge emission (NBE) peak centered at 422 nm, which was blue-shifted in comparison to that of the bulk ZnSe, which was mainly caused by the quantum confinement effect. However, the zinc blende ZnSe nanoparticles exhibited a near-band-edge luminescence peak centered at 472 nm. 2012 Elsevier Ltd. All rights reserved.
收录类别SCI ; EI
WOS记录号WOS:000315608400019
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被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/40589
专题中科院长春光机所知识产出
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Feng B.,Yang J.,Cao J.,et al. Controllable synthesis, growth mechanism and optical properties of the ZnSe quantum dots and nanoparticles with different crystalline phases[J]. Materials Research Bulletin,2013,48(3).
APA Feng B..,Yang J..,Cao J..,Yang L..,Gao M..,...&Song H..(2013).Controllable synthesis, growth mechanism and optical properties of the ZnSe quantum dots and nanoparticles with different crystalline phases.Materials Research Bulletin,48(3).
MLA Feng B.,et al."Controllable synthesis, growth mechanism and optical properties of the ZnSe quantum dots and nanoparticles with different crystalline phases".Materials Research Bulletin 48.3(2013).
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