Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations

	Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations
	Liu D.; Lu Y.; Li Y.-G.; Tan H.-Q.; Chen W.-L.; Zhang Z.-M.; Wang E.-B.
	2013
发表期刊	Dalton Transactions
ISSN	ISBN/14779226
卷号	42 期号:40
摘要	Three trimeric polyoxovanadate based on 1:13 anions [MnV13O 38]7- with lanthanide cations Ln3+ (Ln = La, Ce and Nd) and pyridine-3-carboxylic acid: HK3{[Ln(H2O) 4]6[MnV13O38]3(SO 4)2}·3(C6H6NO 2)·nH2O (Ln = La 1, Nd 3; n = 33 for 1, 20 for 3), H2.5K1.5{[Ce(H2O)4] 6[MnV13O38]3(SO4) 2}·3(C6H6NO2)·20. 5H2O (2) (C6H5NO2 = pyridine-3-carboxylic acid) have been synthesized and characterized by elemental analysis, IR spectroscopy, UV spectroscopy, TG analysis, XPRD, electrochemical analyses, magnetism and single-crystal X-ray diffraction. Compounds 1-3 are isostructural and crystallized in the hexagonal system, space group P6 3/m. Compounds 1-3 contain an unusual trimeric polyoxoanion [{Ln 2MnV13O38}3(SO4) 2]7-, representing the first polyoxovanadate-based trimeric aggregate with rare earth ions. The electrochemical and electrocatalytic properties of the compounds have been investigated. Magnetic studies indicate that antiferromagnetic interactions exist in the compounds. 2013 The Royal Society of Chemistry.
收录类别	SCI ; EI
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/40560
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Liu D.,Lu Y.,Li Y.-G.,et al. Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations[J]. Dalton Transactions,2013,42(40).
APA	Liu D..,Lu Y..,Li Y.-G..,Tan H.-Q..,Chen W.-L..,...&Wang E.-B..(2013).Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations.Dalton Transactions,42(40).
MLA	Liu D.,et al."Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations".Dalton Transactions 42.40(2013).

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