Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations | |
Liu D.; Lu Y.; Li Y.-G.; Tan H.-Q.; Chen W.-L.; Zhang Z.-M.; Wang E.-B. | |
2013 | |
发表期刊 | Dalton Transactions |
ISSN | ISBN/14779226 |
卷号 | 42期号:40 |
摘要 | Three trimeric polyoxovanadate based on 1:13 anions [MnV13O 38]7- with lanthanide cations Ln3+ (Ln = La, Ce and Nd) and pyridine-3-carboxylic acid: HK3{[Ln(H2O) 4]6[MnV13O38]3(SO 4)2}·3(C6H6NO 2)·nH2O (Ln = La 1, Nd 3; n = 33 for 1, 20 for 3), H2.5K1.5{[Ce(H2O)4] 6[MnV13O38]3(SO4) 2}·3(C6H6NO2)·20. 5H2O (2) (C6H5NO2 = pyridine-3-carboxylic acid) have been synthesized and characterized by elemental analysis, IR spectroscopy, UV spectroscopy, TG analysis, XPRD, electrochemical analyses, magnetism and single-crystal X-ray diffraction. Compounds 1-3 are isostructural and crystallized in the hexagonal system, space group P6 3/m. Compounds 1-3 contain an unusual trimeric polyoxoanion [{Ln 2MnV13O38}3(SO4) 2]7-, representing the first polyoxovanadate-based trimeric aggregate with rare earth ions. The electrochemical and electrocatalytic properties of the compounds have been investigated. Magnetic studies indicate that antiferromagnetic interactions exist in the compounds. 2013 The Royal Society of Chemistry. |
收录类别 | SCI ; EI |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/40560 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Liu D.,Lu Y.,Li Y.-G.,et al. Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations[J]. Dalton Transactions,2013,42(40). |
APA | Liu D..,Lu Y..,Li Y.-G..,Tan H.-Q..,Chen W.-L..,...&Wang E.-B..(2013).Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations.Dalton Transactions,42(40). |
MLA | Liu D.,et al."Assembly of trimeric polyoxovanadate aggregates based on [MnV 13O38]7- building blocks and lanthanide cations".Dalton Transactions 42.40(2013). |
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