Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Thermal modification of wide-bandgap hydrogenated amorphous silicon-carbon alloy films grown by plasma-enhanced chemical vapour deposition from C2H2+SiH4 mixtures | |
Liu Y. C.; Giorgis F.; Pirri C. F. | |
1997 | |
发表期刊 | Philosophical Magazine B-Physics of Condensed Matter Statistical Mechanics Electronic Optical and Magnetic Properties
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ISSN | 0141-8637 |
卷号 | 75期号:4页码:485-496 |
摘要 | The thermal stability of hydrogenated amorphous silicon-carbon (aSi(1-x)C(x):H) alloy films grown by plasma-enhanced chemical vapour deposition from C2H2+SiH4 mixtures was characterized by means of infrared spectroscopy, electron spin resonance, transmittance-reflectance spectroscopy and photoluminescence (PL) spectroscopy. It is demonstrated that the network undergoes relaxation and reconstruction under the condition of low-temperature annealing. Weak C-C, Si-Si and C-Si bonds will be broken, and a new stage of hydrogen effusion and structural rearrangement will occur under the condition of high-temperature annealing. The thermal stability a-Si1-xCx:H of films increases with increase in carbon content. In carbon-poor a-Si1-xCx:H networks, the dangling bonds are the main non-radiative recombination channel, which causes a strong correlation of the PL signal with defect density. In carbon-rich a-Si1-xCx:H networks, pi-bonded clusters play an important role in the luminescence process. The PL intensity has little dependence on defects in carbon-rich a-Si1-xCx:H. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/34469 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Liu Y. C.,Giorgis F.,Pirri C. F.. Thermal modification of wide-bandgap hydrogenated amorphous silicon-carbon alloy films grown by plasma-enhanced chemical vapour deposition from C2H2+SiH4 mixtures[J]. Philosophical Magazine B-Physics of Condensed Matter Statistical Mechanics Electronic Optical and Magnetic Properties,1997,75(4):485-496. |
APA | Liu Y. C.,Giorgis F.,&Pirri C. F..(1997).Thermal modification of wide-bandgap hydrogenated amorphous silicon-carbon alloy films grown by plasma-enhanced chemical vapour deposition from C2H2+SiH4 mixtures.Philosophical Magazine B-Physics of Condensed Matter Statistical Mechanics Electronic Optical and Magnetic Properties,75(4),485-496. |
MLA | Liu Y. C.,et al."Thermal modification of wide-bandgap hydrogenated amorphous silicon-carbon alloy films grown by plasma-enhanced chemical vapour deposition from C2H2+SiH4 mixtures".Philosophical Magazine B-Physics of Condensed Matter Statistical Mechanics Electronic Optical and Magnetic Properties 75.4(1997):485-496. |
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