SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE

	SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE
其他题名	论文其他题名
	Wang R. F.; Jin L. P.; Wang M. Z.; Huang S. H.; Chen X. T.
	1995
发表期刊	Acta Chimica Sinica
ISSN	0567-7351
卷号	53 期号:1 页码:39-45
摘要	The coordination compound of europium p-methylbenzoate with 2,2 '-dipyridine was synthesized and characterized by elemental analysis and infrared spectrum. The crystal structure of the title compound, Eu-2(p-MBA)(6)(dipy)(2) (p-MBA: p-methylbenzoate, dipy: 2,2 '-dipyridine) was determined by the X ray diffraction analysis. It crystallizes in the monoclinic C2/c system with unit cell dimensions a=1.4086(6), b=1.9115(11), c=2.3077(16)nm; beta=96.60(4)degrees, V=6.1727nm(3) and Z=4. The metal atoms are octa-coordinated with the bidentates of p-methylbenzoate and 2,2 '-dipyridine. Since the title coordination compound Eu(p-MBA), dipy fluoresces very intensely under ultraviolet or visible light. Using Eu(III) ion as luminescent probe, the high-resolution laser excited excitation and luminescence spectra and time resolved spectra were recorded at 77K. The emission spectra indicate that two Eu(III) ion sites are present in the compound .
收录类别	SCI
语种	中文
WOS记录号	WOS:A1995QH85200007
引用统计
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/25968
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Wang R. F.,Jin L. P.,Wang M. Z.,et al. SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE[J]. Acta Chimica Sinica,1995,53(1):39-45.
APA	Wang R. F.,Jin L. P.,Wang M. Z.,Huang S. H.,&Chen X. T..(1995).SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE.Acta Chimica Sinica,53(1),39-45.
MLA	Wang R. F.,et al."SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE".Acta Chimica Sinica 53.1(1995):39-45.

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