Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Synthesis of soluble rare-earth metal bisphthalocyanines and their Langmuir-Blodgett films for gas sensibility | |
其他题名 | 论文其他题名 |
Liang B. J.; Yuan C. W.; Wei Y.; Zhang Y.; Jiang D. P.; Zhang S. G.; Lu A. D. | |
1997 | |
发表期刊 | Synthetic Metals |
ISSN | 0379-6779 |
卷号 | 88期号:3页码:219-223 |
摘要 | In the present work, the synthesis of octa-4-(2,4-di-tert-pentylphenoxyl)-substituted rare-earth bisphthalocyanine with Sm, Er and Nd as central metal atom, respectively, is described. These compounds have improved solubility in organic solvents, and can form homogenous and relatively stable films at the air/water interface. The Langmuir film can be transferred by vertical dipping onto substrates with Z-type configuration. In Langmuir-Blodgett (LB) films, rare-earth bisphthalocyanine molecules exist mainly in associated species. The absorption increases linearly with the number of deposited layers indicating reproducible quality, and the layers adhere tenaciously to substrates and to each other. The gas sensibility of the films was investigated. The LB films of Sm and Er bisphthalocyanines have sensibility for the vapors of NH3 and NO2, but that of Nd bisphthalocyanine exhibits sensibility and selectivity only for the vapor of NH3. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25399 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Liang B. J.,Yuan C. W.,Wei Y.,et al. Synthesis of soluble rare-earth metal bisphthalocyanines and their Langmuir-Blodgett films for gas sensibility[J]. Synthetic Metals,1997,88(3):219-223. |
APA | Liang B. J..,Yuan C. W..,Wei Y..,Zhang Y..,Jiang D. P..,...&Lu A. D..(1997).Synthesis of soluble rare-earth metal bisphthalocyanines and their Langmuir-Blodgett films for gas sensibility.Synthetic Metals,88(3),219-223. |
MLA | Liang B. J.,et al."Synthesis of soluble rare-earth metal bisphthalocyanines and their Langmuir-Blodgett films for gas sensibility".Synthetic Metals 88.3(1997):219-223. |
条目包含的文件 | 下载所有文件 | |||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Liang-1997-Synthesis(270KB) | 开放获取 | -- | 浏览 下载 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论