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Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid
其他题名论文其他题名
Wang Y. B.; Zhuang W. J.; Jin L. P.; Lu S. Z.
2004
发表期刊Journal of Molecular Structure
ISSN0022-2860
卷号705期号:1—3页码:21-27
摘要First examples of lanthanide coordination polymers with 4,4'-biphenyldicarboxylic acid (4,4'-H(2)bpdc), Ln(4,4'-Hbpdc)(4,4'-bpdc)(H2O)(2) (Ln = Pr(1), Eu(2), Gd(3)) and Er(4,4'-bpdc)(1.5)(H2O)(2) (4) were prepared by the solvothermal synthesis. Crystallographic data show that complexes 1-3 are isostructural and each lanthanide(III) ion is coordinated to six 4,4'-Hbpdc ligands, and display 3D sandwich structure with lanthanide ion layers and organic ligand layers alternately linking up with each other. Complex 4 shows different coordination modes of 4,4'-bpdc ligands from 1-3 and each Er(III) ion is attached to four 4,4'-bpdc ligands to construct 3D sandwich structure. The emission spectrum of 2 shows one Eu3+ ion site, which is consistent with the results of the X-ray crystal structure analysis. (C) 2004 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/25092
专题中科院长春光机所知识产出
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Wang Y. B.,Zhuang W. J.,Jin L. P.,et al. Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid[J]. Journal of Molecular Structure,2004,705(1—3):21-27.
APA Wang Y. B.,Zhuang W. J.,Jin L. P.,&Lu S. Z..(2004).Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid.Journal of Molecular Structure,705(1—3),21-27.
MLA Wang Y. B.,et al."Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid".Journal of Molecular Structure 705.1—3(2004):21-27.
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