Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid | |
其他题名 | 论文其他题名 |
Wang Y. B.; Zhuang W. J.; Jin L. P.; Lu S. Z. | |
2004 | |
发表期刊 | Journal of Molecular Structure
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ISSN | 0022-2860 |
卷号 | 705期号:1—3页码:21-27 |
摘要 | First examples of lanthanide coordination polymers with 4,4'-biphenyldicarboxylic acid (4,4'-H(2)bpdc), Ln(4,4'-Hbpdc)(4,4'-bpdc)(H2O)(2) (Ln = Pr(1), Eu(2), Gd(3)) and Er(4,4'-bpdc)(1.5)(H2O)(2) (4) were prepared by the solvothermal synthesis. Crystallographic data show that complexes 1-3 are isostructural and each lanthanide(III) ion is coordinated to six 4,4'-Hbpdc ligands, and display 3D sandwich structure with lanthanide ion layers and organic ligand layers alternately linking up with each other. Complex 4 shows different coordination modes of 4,4'-bpdc ligands from 1-3 and each Er(III) ion is attached to four 4,4'-bpdc ligands to construct 3D sandwich structure. The emission spectrum of 2 shows one Eu3+ ion site, which is consistent with the results of the X-ray crystal structure analysis. (C) 2004 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25092 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Wang Y. B.,Zhuang W. J.,Jin L. P.,et al. Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid[J]. Journal of Molecular Structure,2004,705(1—3):21-27. |
APA | Wang Y. B.,Zhuang W. J.,Jin L. P.,&Lu S. Z..(2004).Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid.Journal of Molecular Structure,705(1—3),21-27. |
MLA | Wang Y. B.,et al."Solvothermal synthesis and structures of lanthanide-organic sandwich coordination polymers with 4,4 '-biphenyldicarboxylic acid".Journal of Molecular Structure 705.1—3(2004):21-27. |
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