Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning | |
其他题名 | 论文其他题名 |
Dong B.; Song H. W.; Yu H. Q.; Zhang H.; Qin R. F.; Bai X.; Pan G. H.; Lu S. Z.; Wang F.; Fan L. B.; Dai Q. L. | |
2008 | |
发表期刊 | Journal of Physical Chemistry C
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ISSN | 1932-7447 |
卷号 | 112期号:5页码:1435-1440 |
摘要 | Ln(3+) doped (Yb3+,Tm3+ codoped and Yb3+,Er3+,Tm3+ tridoped) NaYF4/poly(vinyl pyrrolidone)(PVP) (M-w approximate to 5 1300 000) composite fibers with an average diameter of 300-800 nm were prepared by electrospinning and characterized by X-ray diffraction, field emission scanning electron micrography, and Fourier transform infrared spectra. Their upconversion (UC) luminescence properties were studied in contrast to the corresponding Ln(3+) doped NaYF4 nanoparticles (15-20 nm) under 980-nm excitation. The results demonstrate that in the Yb3+,TM3+ codoped composite fibers the blue emission of (1)G(4)-H-1(6) is dominantly strong, while in the nanoparticles the red emission of F-3(2,3)-H-3(6) Contributes considerably to the increase of the excitation power. This indicates that the color purity of blue is improved greatly by the modification of PVP. In the tridoped Yb3+,Er3+, TM3+ composite fibers, white light with more stable color balance (blue (1)G(4)-H-3(6) of Tm3+, green H-2(11/2)/S-4(3/2)-I-4(15/2), and red F-4(9/2)-I-4(15/2) of Er3+) was obtained. The improved UC properties in the composite fibers are attributed to the suppressed local thermal effect. The energy transfer and UC populating processes are discussed. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/24851 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Dong B.,Song H. W.,Yu H. Q.,et al. Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning[J]. Journal of Physical Chemistry C,2008,112(5):1435-1440. |
APA | Dong B..,Song H. W..,Yu H. Q..,Zhang H..,Qin R. F..,...&Dai Q. L..(2008).Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning.Journal of Physical Chemistry C,112(5),1435-1440. |
MLA | Dong B.,et al."Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning".Journal of Physical Chemistry C 112.5(2008):1435-1440. |
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