Switching Optimally Balanced Fe–N Interaction Enables Extremely Stable Energy Storage

doi:10.1002/eem2.12342

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	Switching Optimally Balanced Fe–N Interaction Enables Extremely Stable Energy Storage
	Z. Zhao, W. Zhang, M. Liu, D. Wang, X. Wang, L. Zheng, X. Zou, Z. Wang, D. Li, K. Huang and W. Zheng
	2023
发表期刊	Energy and Environmental Materials
ISSN	25750348
卷号	6 期号:2
摘要	The interaction between electrode materials and charge carriers is one of the central issues dominating underlying energy storage mechanisms. To address the notoriously significant volume changes accompanying intercalation or formation of alloy/compounds, we aim to introduce and utilize a weak, reversible Fe–N interaction during the (de)intercalation of ammonium ions (NH4+) within iron(III) hexacyanoferrate (FeHCF), inspired by manipulating the electrostatic adsorption between N and Fe in the early stages of ammonia synthesis (Bosch-Harber Process, Chemical Engineering) and steel nitriding processes (Metal Industry). Such strategy of switching well-balanced Fe–N interaction is confirmed in between the nitrogen of ammonium ions and high-spin Fe in FeHCF, as observed by using X-ray absorption spectroscopy. The resulting material provided an extremely stable energy storage (58 mAh g−1 after 10 000 cycles at current density of 1 A g−1) as well as high-rate performance (23.6 mAh g−1 at current density of 10 A g−1). © 2022 Zhengzhou University.
DOI	10.1002/eem2.12342
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收录类别	ei
引用统计
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/68252
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	Z. Zhao, W. Zhang, M. Liu, D. Wang, X. Wang, L. Zheng, X. Zou, Z. Wang, D. Li, K. Huang and W. Zheng. Switching Optimally Balanced Fe–N Interaction Enables Extremely Stable Energy Storage[J]. Energy and Environmental Materials,2023,6(2).
APA	Z. Zhao, W. Zhang, M. Liu, D. Wang, X. Wang, L. Zheng, X. Zou, Z. Wang, D. Li, K. Huang and W. Zheng.(2023).Switching Optimally Balanced Fe–N Interaction Enables Extremely Stable Energy Storage.Energy and Environmental Materials,6(2).
MLA	Z. Zhao, W. Zhang, M. Liu, D. Wang, X. Wang, L. Zheng, X. Zou, Z. Wang, D. Li, K. Huang and W. Zheng."Switching Optimally Balanced Fe–N Interaction Enables Extremely Stable Energy Storage".Energy and Environmental Materials 6.2(2023).

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