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Interface designing of efficient Z-scheme Ti-ZnFe2O4/In2O3 photoanode toward boosting photoelectrochemical water oxidation
K. K. Ba, Y. Y. Li, Y. A. Liu, Y. H. Lin, D. J. Wang, T. F. Xie and J. Li
2023
发表期刊Journal of Colloid and Interface Science
ISSN0021-9797
卷号649页码:492-500
摘要Ti-ZnFe2O4 photoanode has attracted extensive attention in photoelectrochemical (PEC) water oxidation due to its narrow band gap and good photostability. However, its low efficiency limits its development. Herein, we designed and constructed direct Z-scheme Ti-ZnFe2O4/In2O3 (Ti-ZFO/In2O3) photoanode. Under the interface electric field, photogenerated holes with stronger oxidation capacity on In2O3 are retained to participate in the water oxidation reaction, and the photocurrent density of Ti-ZFO/In2O3 is much higher than that of pure Ti-ZFO, reaching 2.2 mA/cm2 at 1.23 V vs. RHE. Kelvin Probe, steady-state photovoltage spectroscopy (SPV), transient photovoltage spectroscopy (TPV) and in-situ double beam strategy were used to demonstrate the Z-scheme charge transfer mechanism of Ti-ZFO/In2O3 photoanode. Our work provides an effective scheme and technical means for further understanding the mechanism of interfacial charge transfer.
DOI10.1016/j.jcis.2023.06.100
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收录类别sci
语种英语
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文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/67327
专题中国科学院长春光学精密机械与物理研究所
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K. K. Ba, Y. Y. Li, Y. A. Liu, Y. H. Lin, D. J. Wang, T. F. Xie and J. Li. Interface designing of efficient Z-scheme Ti-ZnFe2O4/In2O3 photoanode toward boosting photoelectrochemical water oxidation[J]. Journal of Colloid and Interface Science,2023,649:492-500.
APA K. K. Ba, Y. Y. Li, Y. A. Liu, Y. H. Lin, D. J. Wang, T. F. Xie and J. Li.(2023).Interface designing of efficient Z-scheme Ti-ZnFe2O4/In2O3 photoanode toward boosting photoelectrochemical water oxidation.Journal of Colloid and Interface Science,649,492-500.
MLA K. K. Ba, Y. Y. Li, Y. A. Liu, Y. H. Lin, D. J. Wang, T. F. Xie and J. Li."Interface designing of efficient Z-scheme Ti-ZnFe2O4/In2O3 photoanode toward boosting photoelectrochemical water oxidation".Journal of Colloid and Interface Science 649(2023):492-500.
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