Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets

doi:10.1021/acs.jpcc.2c00531

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	Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets
	Y. Zhang; L. X. Wang; G. C. Zheng; S. Y. Lyu; Y. Zhang and K. A. Chang
	2022
发表期刊	Journal of Physical Chemistry C
ISSN	1932-7447
卷号	126 期号:27 页码:11129-11137
摘要	ABSTRACT: In this article, we address subnanometer resolved fluorescence imaging of single molecule inside a plasmonic picocavity by proposing a semiclassical theory via combining the macroscopic quantum electrodynamics theory and the open quantum system theory. To gain insights into the experimental 020-0677-y], we have further equipped this theory with the classical electromagnetic simulation of the picocavity, formed by atomistic cluster-decorated silver STM tip and a silver substrate, and the time-dependent density functional theory calculation of zinc phthalocyanine molecule. Our simulations not only reproduce the fluorescence spectrum and imaging as measured in the experiment, confirming the influence of extreme field confinement afforded by the picocavity, but also predict Rabi oscillation dynamics and Mollow triplets spectrum for moderate laser excitation. Thus, our study highlights the possibility of coherently manipulating the molecular state and exploring quantum optical phenomena with the plasmonic picocavity.
DOI	10.1021/acs.jpcc.2c00531
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收录类别	sci ; ei
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/66990
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	Y. Zhang,L. X. Wang,G. C. Zheng,et al. Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets[J]. Journal of Physical Chemistry C,2022,126(27):11129-11137.
APA	Y. Zhang,L. X. Wang,G. C. Zheng,S. Y. Lyu,&Y. Zhang and K. A. Chang.(2022).Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets.Journal of Physical Chemistry C,126(27),11129-11137.
MLA	Y. Zhang,et al."Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets".Journal of Physical Chemistry C 126.27(2022):11129-11137.

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