Changchun Institute of Optics,Fine Mechanics and Physics,CAS
A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries | |
G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan | |
2020 | |
发表期刊 | Nanoscale |
ISSN | 2040-3364 |
卷号 | 12期号:48页码:9 |
摘要 | The rapid capacity loss caused by the shuttling effect of polysulfides is one of the great challenges of Li-S batteries. In this work, we adopted a simple solid-phase sintering method to synthesize titanium disulfide (TiS2) and further demonstrated it as a superior modifier of separators for Li-S batteries. Two commonly adopted modification processes of separators, including vacuum filtration (VF) and slurry casting (SC) have been used to prepare TiS2/Celgard separators. TiS2-VF/Celgard can better restrain the polysulfide shuttling effect compared with TiS2-SC/Celgard. A TiS2-VF/Celgard-based Li-S battery has a reversible capacity of 771.6 mA h g(-1), with a capacity retention of 645.6 mA h g(-1) after 500 cycles at 2.0 C, corresponding to a capacity fading rate of similar to 0.033% per cycle. This study has shown the potential of TiS2 as a multifunctional modifier of separators for high performance and long cycle life Li-S batteries. |
DOI | 10.1039/d0nr06429g |
URL | 查看原文 |
收录类别 | SCI ; EI |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/64967 |
专题 | 中国科学院长春光学精密机械与物理研究所 |
推荐引用方式 GB/T 7714 | G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan. A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries[J]. Nanoscale,2020,12(48):9. |
APA | G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan.(2020).A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries.Nanoscale,12(48),9. |
MLA | G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan."A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries".Nanoscale 12.48(2020):9. |
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A TiS2_Celgard separ(4835KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 |
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