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A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries
G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan
2020
发表期刊Nanoscale
ISSN2040-3364
卷号12期号:48页码:9
摘要The rapid capacity loss caused by the shuttling effect of polysulfides is one of the great challenges of Li-S batteries. In this work, we adopted a simple solid-phase sintering method to synthesize titanium disulfide (TiS2) and further demonstrated it as a superior modifier of separators for Li-S batteries. Two commonly adopted modification processes of separators, including vacuum filtration (VF) and slurry casting (SC) have been used to prepare TiS2/Celgard separators. TiS2-VF/Celgard can better restrain the polysulfide shuttling effect compared with TiS2-SC/Celgard. A TiS2-VF/Celgard-based Li-S battery has a reversible capacity of 771.6 mA h g(-1), with a capacity retention of 645.6 mA h g(-1) after 500 cycles at 2.0 C, corresponding to a capacity fading rate of similar to 0.033% per cycle. This study has shown the potential of TiS2 as a multifunctional modifier of separators for high performance and long cycle life Li-S batteries.
DOI10.1039/d0nr06429g
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收录类别SCI ; EI
语种英语
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文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/64967
专题中国科学院长春光学精密机械与物理研究所
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G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan. A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries[J]. Nanoscale,2020,12(48):9.
APA G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan.(2020).A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries.Nanoscale,12(48),9.
MLA G. F. S. Yan,C. Xu,Z. H. Meng,M. Z. Hou,W. Yan,N. B. Lin,L. F. Lai and D. Zhan."A TiS2/Celgard separator as an efficient polysulfide shuttling inhibitor for high-performance lithium-sulfur batteries".Nanoscale 12.48(2020):9.
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