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Thermal evolution and migration behavior of ion-implanted nitrogen in ZnO:In-N films
H. Zhang,W. J. Li,G. P. Qin,H. B. Ruan,D. Wang,J. Wang,Z. Huang,F. Wu,C. Y. Kong and L. Fang
2020
发表期刊Applied Surface Science
ISSN0169-4332
卷号509页码:8
摘要Thermal evolution and migration behavior of nitrogen (N) dopants in indium (In) doped ZnO films implanted with high-dose N ions (ZnO:In-N) were investigated by means of experiment and first-principles calculations. The results demonstrate that N-dopants have poor thermal stability, which has a significant impact on N local chemical states. In particular, two different temperature regions can clearly be distinguished in the annealing process. At low-temperature region, the interaction of substitutional nitrogen (N-o) acceptor and interstitial nitrogen (N-i) starts to occur, which leads to a decrease in N-o acceptor and the formation of additional molecular nitrogen at oxygen site [(N-2)(o)]. In contrast, at high-temperature region, annealing favors energetically the generation of abundant oxygen vacancies near the surface and simultaneously induces the serious out-diffusion of N-dopants. Combined with the calculated migration barriers, oxygen vacancies are deemed to assist the out-diffusion of N-dopants via a vacancy mechanism. This work provides insights into the formation and evolution of different N-related defects and their interaction with intrinsic defects.
DOI10.1016/j.apsusc.2019.144793
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收录类别SCI ; EI
语种英语
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文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/64958
专题中国科学院长春光学精密机械与物理研究所
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H. Zhang,W. J. Li,G. P. Qin,H. B. Ruan,D. Wang,J. Wang,Z. Huang,F. Wu,C. Y. Kong and L. Fang. Thermal evolution and migration behavior of ion-implanted nitrogen in ZnO:In-N films[J]. Applied Surface Science,2020,509:8.
APA H. Zhang,W. J. Li,G. P. Qin,H. B. Ruan,D. Wang,J. Wang,Z. Huang,F. Wu,C. Y. Kong and L. Fang.(2020).Thermal evolution and migration behavior of ion-implanted nitrogen in ZnO:In-N films.Applied Surface Science,509,8.
MLA H. Zhang,W. J. Li,G. P. Qin,H. B. Ruan,D. Wang,J. Wang,Z. Huang,F. Wu,C. Y. Kong and L. Fang."Thermal evolution and migration behavior of ion-implanted nitrogen in ZnO:In-N films".Applied Surface Science 509(2020):8.
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