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Non-axial N-O-V-Zn shallow acceptor complexes in nitrogen implanted p-type ZnO thin films
W. J. Li,H. Zhang,X. Y. Zhang,G. P. Qin,H. L. Li,Y. Q. Xiong,L. J. Ye,H. B. Ruan,C. Z. Tong,C. Y. Kong and L. Fang
2020
发表期刊Applied Surface Science
ISSN0169-4332
卷号529页码:6
摘要Over the past two decades, there have been numerous reports about the p-type behavior of N-doped ZnO. To date, however, its origin still remains mysterious, especially, N ion-implanted ZnO system. Herein, ZnO films were implanted with 70 keV N ions to a fluence of 1x10(17) cm(-2) at room temperature, followed by annealing in the range of 750-950 degrees C. The obtained p-type ZnO films have a widely hole concentration of 2.87 x 10(15) similar to 2.64 x1016 cm(-3), a mobility of 1.37 similar to 7.27 cm(2)V(-1)s(-1) and a resistivity of 148.3 similar to 299.4 Omega.cm. The thermal evolution of point defects and the possible shallow acceptors in N-implanted ZnO films were further investigated by means of Raman scattering, Photoluminescence (PL) and Electron paramagnetic resonance (EPR). The results show that abundant intrinsic-related defects including zinc interstitials (Zn-i), oxygen vacancies (V-O) and zinc vacancies (V-Zn) were introduced during ion implantation. It is demonstrated that appropriate post-annealing can not only reduce the compensation of donor defects, but also facilitate the formation of N-related shallow acceptor complexes, both of which contribute to the p-type conduction transition of N-implanted ZnO films. The non-axial N-O-V-Zn complexes are proposed to be a kind of potential and stable acceptors in N ion-implanted ZnO films.
DOI10.1016/j.apsusc.2020.147168
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收录类别SCI
语种英语
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文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/64720
专题中国科学院长春光学精密机械与物理研究所
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W. J. Li,H. Zhang,X. Y. Zhang,G. P. Qin,H. L. Li,Y. Q. Xiong,L. J. Ye,H. B. Ruan,C. Z. Tong,C. Y. Kong and L. Fang. Non-axial N-O-V-Zn shallow acceptor complexes in nitrogen implanted p-type ZnO thin films[J]. Applied Surface Science,2020,529:6.
APA W. J. Li,H. Zhang,X. Y. Zhang,G. P. Qin,H. L. Li,Y. Q. Xiong,L. J. Ye,H. B. Ruan,C. Z. Tong,C. Y. Kong and L. Fang.(2020).Non-axial N-O-V-Zn shallow acceptor complexes in nitrogen implanted p-type ZnO thin films.Applied Surface Science,529,6.
MLA W. J. Li,H. Zhang,X. Y. Zhang,G. P. Qin,H. L. Li,Y. Q. Xiong,L. J. Ye,H. B. Ruan,C. Z. Tong,C. Y. Kong and L. Fang."Non-axial N-O-V-Zn shallow acceptor complexes in nitrogen implanted p-type ZnO thin films".Applied Surface Science 529(2020):6.
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