Thermally Activated Upconversion Near-Infrared Photoluminescence from Carbon Dots Synthesized via Microwave Assisted Exfoliation

doi:10.1002/smll.201905050

CIOMP OpenIR

	Thermally Activated Upconversion Near-Infrared Photoluminescence from Carbon Dots Synthesized via Microwave Assisted Exfoliation
	D.Li; C.Liang; E.V.Ushakova; M.H.Sun; X.D.Huang; X.Y.Zhang
	2019
发表期刊	Small
ISSN	1613-6810
卷号	15 期号:50 页码:7
摘要	Upconversion near-infrared (NIR) fluorescent carbon dots (CDs) are important for imaging applications. Herein, thermally activated upconversion photoluminescence (UCPL) in the NIR region, with an emission peak at 784 nm, which appears under 808 nm continuous-wave laser excitation, are realized in the NIR absorbing/emissive CDs (NIR-CDs). The NIR-CDs are synthesized by microwave-assisted exfoliation of red emissive CDs in dimethylformamide, and feature single or few-layered graphene-like cores. This structure provides an enhanced contact area of the graphene-like plates in the core with the electron-acceptor carbonyl groups in dimethylformamide, which contributes to the main NIR absorption band peaked at 724 nm and a tail band in 800-850 nm. Temperature-dependent photoluminescence spectra and transient absorption spectra confirm that the UCPL of NIR-CDs is due to the thermally activated electron transitions in the excited state, rather than the multiphoton absorption process. Temperature dependent upconversion NIR luminescence imaging is demonstrated for NIR-CDs embedded in a polyvinyl pyrrolidone film, and the NIR upconversion luminescence imaging in vivo using NIR-CDs in a mouse model is accomplished.
关键词	carbon dots,exfoliation,near-infrared absorption,near-infrared,photoluminescence,upconversion photoluminescence,graphene quantum dots,fluorescence
DOI	10.1002/smll.201905050
URL	查看原文
收录类别	SCI ; EI
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/63275
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	D.Li,C.Liang,E.V.Ushakova,et al. Thermally Activated Upconversion Near-Infrared Photoluminescence from Carbon Dots Synthesized via Microwave Assisted Exfoliation[J]. Small,2019,15(50):7.
APA	D.Li,C.Liang,E.V.Ushakova,M.H.Sun,X.D.Huang,&X.Y.Zhang.(2019).Thermally Activated Upconversion Near-Infrared Photoluminescence from Carbon Dots Synthesized via Microwave Assisted Exfoliation.Small,15(50),7.
MLA	D.Li,et al."Thermally Activated Upconversion Near-Infrared Photoluminescence from Carbon Dots Synthesized via Microwave Assisted Exfoliation".Small 15.50(2019):7.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Thermally Activated （2066KB）	期刊论文	出版稿	开放获取	CC BY-NC-SA	浏览下载