Two-dimensional polymers with versatile functionalities via gemini monomers

doi:10.1126/sciadv.aaw9120

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	Two-dimensional polymers with versatile functionalities via gemini monomers
	Y.Li; H.M.Gao; H.Yu; K.Jiang; H.Yu; Y.Yang; Y.Song; W.K.Zhang
	2019
发表期刊	Science Advances
ISSN	2375-2548
卷号	5 期号:11 页码:13
摘要	Two-dimensional synthetic polymers (2DSPs) are sheet-like macromolecules consisting of covalently linked repeat units in two directions. Access to 2DSPs with controlled size and shape and diverse functionality has been limited because of the need for monomers to retain their crystallinity throughout polymerization. Here, we describe a synthetic strategy for 2DSPs that obviates the need for crystallinity, via the free radical copolymerization of amphiphilic gemini monomers and their monomeric derivatives arranged in a bilayer at solid-liquid interfaces. The ease of this strategy allowed the preparation of 2DSPs with well-controlled size and shape and diverse functionality on solid templates composed of various materials with wide-ranging surface curvatures and dimensions. The resulting 2DSPs showed remarkable mechanical strength and have multiple applications, such as nanolithographic resist and antibacterial agent. The broad scope of this approach markedly expands the chemistry, morphology, and functionality of 2DSPs accessible for practical applications.
关键词	aqueous-solution,cationic gemini,lipid-bilayers,surfactants,polymerizations
DOI	10.1126/sciadv.aaw9120
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收录类别	SCI ; EI
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/63240
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	Y.Li,H.M.Gao,H.Yu,et al. Two-dimensional polymers with versatile functionalities via gemini monomers[J]. Science Advances,2019,5(11):13.
APA	Y.Li.,H.M.Gao.,H.Yu.,K.Jiang.,H.Yu.,...&W.K.Zhang.(2019).Two-dimensional polymers with versatile functionalities via gemini monomers.Science Advances,5(11),13.
MLA	Y.Li,et al."Two-dimensional polymers with versatile functionalities via gemini monomers".Science Advances 5.11(2019):13.

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