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Raman Spectroscopic Investigation of Sulfates Using Mosaic Grating Spatial Heterodyne Raman Spectrometer
J.Qiu; X.T.Li; X.D.Qi
2019
发表期刊Ieee Photonics Journal
ISSN1943-0655
卷号11期号:5页码:12
摘要We introduce a field-widened spatial heterodyne Raman spectrometer with a mosaic grating structure to investigate the broadband Raman spectra of sulfates. The broadband static spatial heterodyne Raman spectrometer configuration employs two mosaic gratings instead of the diffraction gratings to divide the broadband Raman spectrum into two bands. It is able to record high-resolution, broadband Raman spectrum range, covering 5740 cm(-1) with 3.061 cm(-1) spectral resolution using a regular CCD in a single-shot measurement. Raman spectra of mineral sulfates (celestine, gypsum) are investigated. This is the first time to conduct this Raman spectroscopic experiments to investigate the sulfates using the spatial heterodyne Raman spectroscopy. The sodium, potassium and ammonium sulfates at solid state and in aqueous solutions had been detected and analyzed. The effects of metal ions (K+, Na+, NH4+, Ca2+, Sr2+) on vibration of sulfate anion SO42- were discussed. The main v(1) mode can be probed by the spatial heterodyne Raman spectroscopy to determine the concentration of sulfate and unambiguous identification of different sulfate minerals, solid sulfates.
关键词Spectroscopy,spatial heterodyne spectrometer,broadband,high-resolution,field widening,Engineering,Optics,Physics
DOI10.1109/jphot.2019.2939222
收录类别SCI ; EI
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/63109
专题中国科学院长春光学精密机械与物理研究所
推荐引用方式
GB/T 7714
J.Qiu,X.T.Li,X.D.Qi. Raman Spectroscopic Investigation of Sulfates Using Mosaic Grating Spatial Heterodyne Raman Spectrometer[J]. Ieee Photonics Journal,2019,11(5):12.
APA J.Qiu,X.T.Li,&X.D.Qi.(2019).Raman Spectroscopic Investigation of Sulfates Using Mosaic Grating Spatial Heterodyne Raman Spectrometer.Ieee Photonics Journal,11(5),12.
MLA J.Qiu,et al."Raman Spectroscopic Investigation of Sulfates Using Mosaic Grating Spatial Heterodyne Raman Spectrometer".Ieee Photonics Journal 11.5(2019):12.
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