| Realization of the Photostable Intrinsic Core Emission from Carbon Dots through Surface Deoxidation by Ultraviolet Irradiation |
| M.H.Sun; C.Liang; Z.Tian; E.V.Ushakova; D.Li; G.C.Xing
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| 2019
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| 发表期刊 | Journal of Physical Chemistry Letters
(IF:6.71[JCR-2019],7.811[5-Year]) |
| ISSN | 1948-7185
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| 卷号 | 10期号:11页码:3094-3100 |
| 摘要 | It is of a primary importance to realize the intrinsic emission from the inner carbogenic cores of carbon dots (CDs). In this work, CDs with three emission centers were synthesized by a microwave-assisted method using phloroglucinol as a precursor. The emission of these three centers has been identified as originating from molecular fluorophores, surface states of CDs, and the intrinsic CD core state. The emission from molecular fluorophores and from the surface state of CDs exhibited a weak photostability and could be photobleached as a result of UV laser irradiation. The emission from the intrinsic state of the inner carbogenic core has been found to be stable against photobleaching. On the basis of this difference in photostability, we demonstrate how the surface of CDs can be deoxidized under prolonged UV irradiation, resulting in a narrow intrinsic emission with a photoluminescence quantum yield of 17%. |
| 关键词 | light-emitting-diodes,blue luminescence,quantum dots,graphene,graphite,red,fluorescence,mechanism,green,Chemistry,Science & Technology - Other Topics,Materials Science,Physics
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| DOI | 10.1021/acs.jpclett.9b00842
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| 收录类别 | SCI
; EI
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| 语种 | 英语
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| 引用统计 | 正在获取...
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| 文献类型 | 期刊论文
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| 条目标识符 | http://ir.ciomp.ac.cn/handle/181722/63058
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| 专题 | 中国科学院长春光学精密机械与物理研究所
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推荐引用方式
GB/T 7714 |
M.H.Sun,C.Liang,Z.Tian,et al. Realization of the Photostable Intrinsic Core Emission from Carbon Dots through Surface Deoxidation by Ultraviolet Irradiation[J]. Journal of Physical Chemistry Letters,2019,10(11):3094-3100.
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| APA |
M.H.Sun,C.Liang,Z.Tian,E.V.Ushakova,D.Li,&G.C.Xing.(2019).Realization of the Photostable Intrinsic Core Emission from Carbon Dots through Surface Deoxidation by Ultraviolet Irradiation.Journal of Physical Chemistry Letters,10(11),3094-3100.
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| MLA |
M.H.Sun,et al."Realization of the Photostable Intrinsic Core Emission from Carbon Dots through Surface Deoxidation by Ultraviolet Irradiation".Journal of Physical Chemistry Letters 10.11(2019):3094-3100.
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