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Multifunctional optical thermometry based on the stark sublevels of Er3+ in CaO-Y2O3: Yb3+/Er-3(+)
G.T.Xiang; X.T.Liu; W.Liu; B.Wang; Z.Liu; S.Jiang; X.J.Zhou
2019
发表期刊Journal of the American Ceramic Society
ISSN0002-7820
卷号103期号:4页码:2540-2547
摘要A conventional high temperature solid state method was utilized to prepare CaO-Y2O3, which is a potential candidate for manufacturing crucible material to melt titanium and titanium alloys with low cost. Meanwhile, Yb3+ ions and Er3+ ions were selected as the sensitizers and activators respectively to dope into CaO-Y2O3, aimed at providing real-time optical thermometry during the preparation process of titanium alloys realized using fluorescence intensity ratio (FIR) technology. The results reveal that a high measurement precision can be acquired by using the Stark sublevels of Er3+ 4F9/2 to measure the temperature with a maximum absolute error of only about 3 K. In addition, by analyzing the dependence of I-4(13/2) -> I-4(15/2) transition on pump power of 980 nm excitation wavelength, it was found that the laser-induced thermal effect has almost no influence on the temperature measurement conducted by using the FIR of the Stark sublevels of Er3+ 4I13/2, which means that a high excitation pump power can be used to obtain strong NIR emission and good signal-to-noise ratio for optical thermometry without the influence of the laser-induced thermal effect. All the results reveal that CaO-Y2O3: Yb3+/Er3+ is an excellent temperature sensing material with high measurement precision.
关键词fluorescence intensity ratio,optical thermometry,upconversion,Yb3+,Er3+,fluorescence intensity ratio,up-conversion luminescence,shape,yb3+,nanoparticles,excitation,behaviors,phosphors,emission,phase,Materials Science
DOI10.1111/jace.16939
收录类别SCI
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/62931
专题中国科学院长春光学精密机械与物理研究所
推荐引用方式
GB/T 7714
G.T.Xiang,X.T.Liu,W.Liu,et al. Multifunctional optical thermometry based on the stark sublevels of Er3+ in CaO-Y2O3: Yb3+/Er-3(+)[J]. Journal of the American Ceramic Society,2019,103(4):2540-2547.
APA G.T.Xiang.,X.T.Liu.,W.Liu.,B.Wang.,Z.Liu.,...&X.J.Zhou.(2019).Multifunctional optical thermometry based on the stark sublevels of Er3+ in CaO-Y2O3: Yb3+/Er-3(+).Journal of the American Ceramic Society,103(4),2540-2547.
MLA G.T.Xiang,et al."Multifunctional optical thermometry based on the stark sublevels of Er3+ in CaO-Y2O3: Yb3+/Er-3(+)".Journal of the American Ceramic Society 103.4(2019):2540-2547.
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