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Upconversion properties and temperature sensing behaviors in visible and near-infrared region based on fluorescence intensity ratio in LuVO4 Yb3+Er3+
Ma, Y.; Xiang, G. T.; Zhang, J. H.; Liu, Z.; Zhou, P.; Liu, W.; Tang, X.; Jiang, S.; Zhou, X. J.; Li, L.; Luo, Y. S.; Jin, Y.
2018
发表期刊Journal of Alloys and Compounds
ISSN0925-8388
卷号769页码:325-331
摘要A high temperature solid state method was used to synthesize the Yb3+ and Er3+ codoped LuVO4. The efficient energy transfer (ET) processes from Yb3+ to Er3+ has been demonstrated by upconversion (UC) spectra, near-infrared (NIR) spectra and lifetime curves. The optimal doping concentration for Yb3+ and Er3+ is 20 mol % and 2 mol %, respectively. Meanwhile, the temperature sensing behaviors in visible and NIR region based on fluorescence intensity ratio (FIR) have been explored in detail. In visible region, the optical thermometry of LuVO4: Yb3+/Er3+ is investigated via the FIR of the two thermally coupled energy levels H-2(11/2) and S-4(3/2) of Er3+, accompanying with a maximal absolute sensitivity S-A of 0.82% K-1 at 423 K. In NIR region, the FIRs of Peak 1 (located at 1595 nm) to Peak 3 (located at 1660 nm) and Peak 2 (located at 1637 nm) to Peak 3, which are all assigned to I-4(13/2) -> I-4(15/2) transition of Er3+, can be well fitted related to the temperature, with the maximal S-A of 1.85% K-1 and 0.62% K-1 respectively. All the results suggest that LuVO4: Yb3+/Er3+ powders is a potential material for optical thermometry in both visible and NIR region based on FIR. (C) 2018 Elsevier B.V. All rights reserved.
关键词Energy transfer Upconversion Fluorescence intensity ratio Optical thermometry LuVO4: Yb3+/Er3+ hydrothermal synthesis hexagonal-phase luminescence er3+ yb3+ nanocrystals thermometry lanthanide phosphor emission Chemistry Materials Science Metallurgy & Metallurgical Engineering
DOI10.1016/j.jallcom.2018.07.368
收录类别SCI ; EI
引用统计
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/61216
专题中国科学院长春光学精密机械与物理研究所
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Ma, Y.,Xiang, G. T.,Zhang, J. H.,et al. Upconversion properties and temperature sensing behaviors in visible and near-infrared region based on fluorescence intensity ratio in LuVO4 Yb3+Er3+[J]. Journal of Alloys and Compounds,2018,769:325-331.
APA Ma, Y..,Xiang, G. T..,Zhang, J. H..,Liu, Z..,Zhou, P..,...&Jin, Y..(2018).Upconversion properties and temperature sensing behaviors in visible and near-infrared region based on fluorescence intensity ratio in LuVO4 Yb3+Er3+.Journal of Alloys and Compounds,769,325-331.
MLA Ma, Y.,et al."Upconversion properties and temperature sensing behaviors in visible and near-infrared region based on fluorescence intensity ratio in LuVO4 Yb3+Er3+".Journal of Alloys and Compounds 769(2018):325-331.
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