Precisely Tailoring Upconversion Dynamics via Energy Migration in Core-Shell Nanostructures

doi:10.1002/anie.201711606

CIOMP OpenIR

	Precisely Tailoring Upconversion Dynamics via Energy Migration in Core-Shell Nanostructures
	Zuo, J.; Sun, D. P.; Tu, L. P.; Wu, Y. N.; Cao, Y. H.; Xue, B.; Zhang, Y. L.; Chang, Y. L.; Liu, X. M.; Kong, X. G.; Buma, W. J.; Meijer, E. J.; Zhang, H.
	2018
发表期刊	Angewandte Chemie-International Edition
ISSN	1433-7851
卷号	57 期号:12 页码:3054-3058
摘要	Upconversion emission dynamics have long been believed to be determined by the activator and its interaction with neighboring sensitizers. Herein this assumption is, however, shown to be invalid for nanostructures. We demonstrate that excitation energy migration greatly affects upconversion emission dynamics. "Dopant ions Q spatial separation" nanostructures are designed as model systems and the intimate link between the random nature of energy migration and upconversion emission time behavior is unraveled by theoretical modelling and confirmed spectroscopically. Based on this new fundamental insight, we have successfully realized fine control of upconversion emission time behavior (either rise or decay process) by tuning the energy migration paths in various specifically designed nanostructures. This result is significant for applications of this type of materials in super resolution spectroscopy, high-density data storage, anti-counterfeiting, and biological imaging.
关键词	core-shell nanostructures energy migration lanthanides luminescence dynamics Monte Carlo simulation upconversion nanocrystals excitation-energy nanoparticles nanocrystals luminescence surface Chemistry
DOI	10.1002/anie.201711606
收录类别	SCI
引用统计
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/60771
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	Zuo, J.,Sun, D. P.,Tu, L. P.,et al. Precisely Tailoring Upconversion Dynamics via Energy Migration in Core-Shell Nanostructures[J]. Angewandte Chemie-International Edition,2018,57(12):3054-3058.
APA	Zuo, J..,Sun, D. P..,Tu, L. P..,Wu, Y. N..,Cao, Y. H..,...&Zhang, H..(2018).Precisely Tailoring Upconversion Dynamics via Energy Migration in Core-Shell Nanostructures.Angewandte Chemie-International Edition,57(12),3054-3058.
MLA	Zuo, J.,et al."Precisely Tailoring Upconversion Dynamics via Energy Migration in Core-Shell Nanostructures".Angewandte Chemie-International Edition 57.12(2018):3054-3058.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Precisely Tailoring （2404KB）	期刊论文	出版稿	开放获取	CC BY-NC-SA	浏览下载