CIOMP OpenIR  > 中科院长春光机所知识产出
The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors
Xiao, W. G.; D. Wu; L. L. Zhang; X. Zhang; Z. D. Hao; G. H. Pan; L. G. Zhang; X. W. Ba and J. H. Zhang
2017
发表期刊Inorganic Chemistry
卷号56期号:16
摘要Forming solid solutions through cation substitution is an efficient way to improve the luminescence properties of Ce3+ or Eu2+ activated phosphors and even to develop new ones, which is badly needed for phosphor-converted white LEDs. Here, we report new color tunable solid solution phosphors based on Eu2+ activated K2Al2B2O7 as a typical case to demonstrate that, besides crystal field splitting of 5d levels, centroid shift and Stokes shift can be dominant in tuning excitation and emission spectra as well as thermal stability of solid solution phosphors, both of which were previously considered to be negligible. Moreover, a general model involving the inductive effect of neighboring cations is proposed to explain the obvious variations in centroid shift and Stokes shift with cation substitution. Our work is propitious for the construction of more reasonable structure-property relations and thus offers theoretical guidance for designing solid solution phosphors.
收录类别sci ; ei
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/59332
专题中科院长春光机所知识产出
推荐引用方式
GB/T 7714
Xiao, W. G.,D. Wu,L. L. Zhang,et al. The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors[J]. Inorganic Chemistry,2017,56(16).
APA Xiao, W. G..,D. Wu.,L. L. Zhang.,X. Zhang.,Z. D. Hao.,...&X. W. Ba and J. H. Zhang.(2017).The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors.Inorganic Chemistry,56(16).
MLA Xiao, W. G.,et al."The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors".Inorganic Chemistry 56.16(2017).
条目包含的文件 下载所有文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
The Inductive Effect(7164KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 下载
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Xiao, W. G.]的文章
[D. Wu]的文章
[L. L. Zhang]的文章
百度学术
百度学术中相似的文章
[Xiao, W. G.]的文章
[D. Wu]的文章
[L. L. Zhang]的文章
必应学术
必应学术中相似的文章
[Xiao, W. G.]的文章
[D. Wu]的文章
[L. L. Zhang]的文章
相关权益政策
暂无数据
收藏/分享
文件名: The Inductive Effect of Neighboring Cations.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。