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Analogous self-assembly and crystallization: a chloride-directed orientated self-assembly of Cu nanoclusters and subsequent growth of Cu2-xS nanocrystals
Liu, J. L.; Y. Tian; Z. N. Wu; L. Ai; Y. Liu; J. L. Cui; W. L. Yu; H. Zhang and B. Yang
2017
发表期刊Nanoscale
卷号9期号:29
摘要Self-assembly and crystallization are two common methods to control the morphologies of nanomaterials, which have many similarities. In this work, chloride is used to direct the self-assembly process of Cu nanoclusters and the subsequent growth of Cu2-xS nanocrystals. Meaningfully, chloride both promotes the transformation of Cu nanocluster self-assembled architectures from one-dimensional (1D) to 2D, and facilitates the transformation of Cu2-xS nanocrystals from nanorods to nanosheets. Such an influence is attributed to the selective adsorption of chloride ions on the specific facets of nanoclusters and nanocrystals, which alters the inter-nanocluster weak interactions during self-assembly and suppresses the activity of Cu2-xS facets during nanocrystal growth. The current results indicate that the method used to direct the morphologies of nanocrystals is extendable to control the tendency of nanocluster self-assembly.
收录类别sci ; ei
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/59075
专题中科院长春光机所知识产出
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Liu, J. L.,Y. Tian,Z. N. Wu,et al. Analogous self-assembly and crystallization: a chloride-directed orientated self-assembly of Cu nanoclusters and subsequent growth of Cu2-xS nanocrystals[J]. Nanoscale,2017,9(29).
APA Liu, J. L..,Y. Tian.,Z. N. Wu.,L. Ai.,Y. Liu.,...&H. Zhang and B. Yang.(2017).Analogous self-assembly and crystallization: a chloride-directed orientated self-assembly of Cu nanoclusters and subsequent growth of Cu2-xS nanocrystals.Nanoscale,9(29).
MLA Liu, J. L.,et al."Analogous self-assembly and crystallization: a chloride-directed orientated self-assembly of Cu nanoclusters and subsequent growth of Cu2-xS nanocrystals".Nanoscale 9.29(2017).
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