Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem

	Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem
	Zhao, S. G.; L. Kang; Y. G. Shen; X. D. Wang; M. A. Asghar; Z. S. Lin; Y. Y. Xu; S. Y. Zeng; M. C. Hong and J. H. Luo
	2016
发表期刊	Journal of the American Chemical Society
卷号	138 期号:9
摘要	A beryllium-free deep-ultraviolet (deep-UV) nonlinear optical (NLO) material K3Ba3Li2Al4B6O20F is developed mainly by the element substitution of Be for Al and Li from Sr2Be2B2O7 that was considered as one of the most promising deep-UV NLO materials. K3Ba3Li2Al4B6O20F preserves the structural merits of Sr2Be2B2O7 and thus exhibits no layering growth tendency and possesses the optical properties required for deep-UV NLO applications, including deep-UV transparency, phase-matchability, and sufficiently large second-harmonic generation (1.5 x KH2PO4). Furthermore, it overcomes the structural instability problem of Sr2Be2B2O7, which is confirmed by the obtainment of large single crystals and phonon dispersion calculations. These attributes make it very attractive for next-generation deep-UV NLO materials. The substitution of Be for Al and Li in beryllium borates provides a new opportunity to design beryllium free deep-UV NLO materials with good performance.
文章类型	期刊
收录类别	SCI ; EI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/57470
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Zhao, S. G.,L. Kang,Y. G. Shen,et al. Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem[J]. Journal of the American Chemical Society,2016,138(9).
APA	Zhao, S. G..,L. Kang.,Y. G. Shen.,X. D. Wang.,M. A. Asghar.,...&M. C. Hong and J. H. Luo.(2016).Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem.Journal of the American Chemical Society,138(9).
MLA	Zhao, S. G.,et al."Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem".Journal of the American Chemical Society 138.9(2016).

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