Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Eu2+-induced enhancement of defect luminescence of ZnS | |
Zhang, X. B. and F. X. Wei | |
2016 | |
发表期刊 | Luminescence |
卷号 | 31期号:8 |
摘要 | Singlet oxygen (O-1(2)), as a reactive oxygen species, has garnered serious attention in physical, chemical, and biological studies. In this paper, we designed and synthesized a new type of singlet-oxygen generation system by exchanging cationic ruthenium complexes (RCs) into anionic bio-MOF-1. The resulting bio-MOF-1&RCs can be used as effective photocatalysts for generation of singlet oxygen under both single-photon and two-photon excitation. Especially, the excellent two-photon absorption (TPA) behavior of bio-MOF-1&RCs aroused our interest greatly because their two-photon absorption band lies in the optical window of biological tissue. Here, we measured the ability of bio-MOF-1&RCs to generate O-1(2) by irradiation under both 490 and 800 nm wavelength light in DMF. 1,3-Diphenylisobenzofuran (DPBF) and 2',7'-dichlorofluorescein (DCFH) were used as typical O-1(2) traps to detect and evaluate the efficiency of generation of O-1(2) under single-photon and two-photon excitation, respectively. Results indicated that bio-MOF-1&[Ru(phen)(3)](2+) was able to effectively generate O-1(2) under both conditions. Our work creates a novel synergistic TPA system with the excellent photophysical properties of RCs and the unique microporous structure benefit of MOFs, which may open a new avenue for creation of a cancer treatment system with both photodynamic therapy and chemotherapy. |
文章类型 | 期刊 |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/57435 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Zhang, X. B. and F. X. Wei. Eu2+-induced enhancement of defect luminescence of ZnS[J]. Luminescence,2016,31(8). |
APA | Zhang, X. B. and F. X. Wei.(2016).Eu2+-induced enhancement of defect luminescence of ZnS.Luminescence,31(8). |
MLA | Zhang, X. B. and F. X. Wei."Eu2+-induced enhancement of defect luminescence of ZnS".Luminescence 31.8(2016). |
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