中国科学院长春光学精密机械与物理研究所

QQ客服 官方微博 反馈留言

	Series of organic-inorganic hybrid rare earth derivatives based on [MnV13O38]7- polyoxoanion: Syntheses, structures, and magnetic and electrochemical properties
	Liu, D.; Y. Lu; H.-Q. Tan; T.-T. Wang and E.-B. Wang
	2015
发表期刊	Crystal Growth and Design
卷号	15期号:1
摘要	A family of polyoxometalate compounds based on 1:13 polyoxoanions [MnV13O38]7-, organic molecules, and lanthanide cations, H[{La2(DMF)5(H2O)4}{MnV13O38}]DMF5H2O (1), H[{Ce2(DMF)2(H2O)7}{MnV13O38}]0.5DMF5.5H2O (2), H2[{K(H2O)2}2{Nd(DMF)(H2O)3}{MnV13O38}]5H2O (3), H[{Ln2(C6H5NO2)3(H2O)6}{[MnV13O38}]C6H5NO210H2O (Ln = La 4, Ce 5), and H2.5[{Pr(C6H5NO2)(H2O)3.5}{Pr0.5(H2O)2}{MnV13O38}]0.5C6H5NO210H2O (6) (DMF = N,N-dimethylformamide; C6H5NO2 = isonicotinic acid), have been obtained utilizing a conventional method of aqueous solution and further characterized by elemental analysis, IR spectrum, UV spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. Compounds 1 and 2 exhibit a one-dimensional extended chain structure constructed by [MnV13O38]7- and lanthanide-organic coordination linkage, while compound 3 reveals three-dimensional (3D) open framework formed by polyoxoanion-lanthanide chains and potassium cations. Compounds 4-6 exhibit 3D supramolecular framework architectures based on [MnV13O38]7- polyoxoanions and lanthanide-organic coordination units. These compounds represent the first examples of extended organic-inorganic hybrids built up by [MnV13O38]7- building blocks and rare earth cations. The influences of the lanthanide contraction effect on the structural alterations from 1 to 3 and from 4 to 6 have been disscussed. The electrochemical and electrocatalytic properties for compounds 1-6 have been studied. Magnetic studies indicate that antiferromagnetic interactions exist in compounds 1-6.
文章类型	期刊
收录类别	EI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/55899
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Liu, D.,Y. Lu,H.-Q. Tan,et al. Series of organic-inorganic hybrid rare earth derivatives based on [MnV13O38]7- polyoxoanion: Syntheses, structures, and magnetic and electrochemical properties[J]. Crystal Growth and Design,2015,15(1).
APA	Liu, D.,Y. Lu,H.-Q. Tan,&T.-T. Wang and E.-B. Wang.(2015).Series of organic-inorganic hybrid rare earth derivatives based on [MnV13O38]7- polyoxoanion: Syntheses, structures, and magnetic and electrochemical properties.Crystal Growth and Design,15(1).
MLA	Liu, D.,et al."Series of organic-inorganic hybrid rare earth derivatives based on [MnV13O38]7- polyoxoanion: Syntheses, structures, and magnetic and electrochemical properties".Crystal Growth and Design 15.1(2015).

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Series of organic-in（9817KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	浏览 下载

个性服务

推荐该条目

保存到收藏夹

查看访问统计

导出为Endnote文件

谷歌学术

谷歌学术中相似的文章

[Liu, D.]的文章

[Y. Lu]的文章

[H.-Q. Tan]的文章

百度学术

百度学术中相似的文章

[Liu, D.]的文章

[Y. Lu]的文章

[H.-Q. Tan]的文章

必应学术

必应学术中相似的文章

[Liu, D.]的文章

[Y. Lu]的文章

[H.-Q. Tan]的文章

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。