Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks | |
Xing, S. H.; G. Zeng; X. M. Liu; F. Yang; Z. Q. Hao; W. Gao; Y. L. Yang; X. R. Wang; G. H. Li; Z. Shi and S. H. Feng | |
2015 | |
发表期刊 | Dalton Transactions
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卷号 | 44期号:20页码:9588-9595 |
摘要 | Two novel lanthanide metal organic frameworks [Eu-4(bpt)(4)(DMF)(2)(H2O)(6)]center dot(DMF)(5)center dot(H2O)(4) (1) and [Tb-4(bpt)(4)(DMF)(2)(H2O)(8)]center dot(DMF)(5)center dot(H2O)(3) (2) were synthesized under hydrothermal conditions, forming a three-dimensional structure (H(3)bpt = biphenyl-3,4',5-tricarboxylate). Single crystal X-ray diffraction reveals that compounds 1 and 2 are heteromorphic and have different topologies due to the change of metal ions with different radii and coordination steric hindrance. The unique luminescence properties of Eu3+ and Tb3+ ions motivated us to dope different amounts of Tb3+ into a single host to obtain light tunable materials. The tunable multicolor emissions, including red, red-orange, orange, yellow and green, can be readily achieved from the doped Ln-MOFs 3-6 by increasing the concentration of Tb3+. In addition, compounds 5 and 6 also exhibit different temperature-dependent luminescence behaviors when the concentration of Eu3+ is low, generating new Ln-MOF thermometers. |
收录类别 | SCI ; EI |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/55486 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Xing, S. H.,G. Zeng,X. M. Liu,et al. Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks[J]. Dalton Transactions,2015,44(20):9588-9595. |
APA | Xing, S. H..,G. Zeng.,X. M. Liu.,F. Yang.,Z. Q. Hao.,...&Z. Shi and S. H. Feng.(2015).Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks.Dalton Transactions,44(20),9588-9595. |
MLA | Xing, S. H.,et al."Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks".Dalton Transactions 44.20(2015):9588-9595. |
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