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Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks
Xiao, L. N.; L. M. Wang; X. N. Shan; H. Y. Guo; L. W. Fu; Y. Y. Hu; X. B. Cui; K. C. Li and J. Q. Xu
2015
Source PublicationCrystengcomm
Volume17Issue:6Pages:1336-1347
AbstractFour new organic-inorganic hybrid compounds, namely, [Cu3(4,4'-bpy)3][HSiW12O40]center dot(C3H4N2) (1), [Cu-3(4,4'-bpy)(3)][PMo12O40]center dot(C5H6N2)center dot 0.5H(2)O (2), [Cu-2(4,4'-bpy)(2)][HPMo12O40]center dot(C5H6N2) (3) and [Cu(Phen)(4,4'-bpy)(H2O)](2)[PW12O40]center dot(4,4'-bpy) (4) (C3H4N2 = imidazole, C5H6N2 = 2-aminopyridine, bpy = bipyridine, Phen = 1,10-phenanthroline), have been synthesized and characterized by IR, UV-vis, powder XRD, cyclic voltammetry analysis, photoluminescence analysis, elemental analyses and single crystal X-ray diffraction. The four compounds represent new examples of secondary organic moiety templated frameworks constructed from Keggin polyanions, metal ions and organic ligands. Compounds 1 and 2 present 3-D framework structures; compound 3 exhibits a 1-D ladder-like structure and compound 4 shows a 2-D layered framework structure. It is noted that the packing structures of compounds 1 and 2 are almost identical; however, the crystal space groups and cell parameters of the two are thoroughly different. Such a phenomenon has also been observed between compound 3 and a compound recently reported by us. Compound 4 is the first framework structure constructed from polyoxometalates, metal ions and mixed organic ligands. In addition, all the four frameworks are combined with dissociated organic moieties as templates.
Indexed BySCI
Document Type期刊论文
Identifierhttp://ir.ciomp.ac.cn/handle/181722/55484
Collection中科院长春光机所知识产出
Recommended Citation
GB/T 7714
Xiao, L. N.,L. M. Wang,X. N. Shan,et al. Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks[J]. Crystengcomm,2015,17(6):1336-1347.
APA Xiao, L. N..,L. M. Wang.,X. N. Shan.,H. Y. Guo.,L. W. Fu.,...&K. C. Li and J. Q. Xu.(2015).Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks.Crystengcomm,17(6),1336-1347.
MLA Xiao, L. N.,et al."Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks".Crystengcomm 17.6(2015):1336-1347.
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