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Temperature and host dependence of the transition interference between f-f and f-d transitions of Sm2+ in matlockites
Pal, P.; H. Hagemann; H. Bill and J. H. Zhang
2015
发表期刊Journal of Luminescence
卷号161页码:323-329
摘要The absorption spectra of Sm2+ doped in MFX (M=Sr, Ba; X=Cl, Br) crystals were studied within the range of 20,000-35,000 cm(-1) as a function of temperature and host The absorption bands observed were described with a simple model developed by Wood and Kaiser using group theory. The temperature and host dependence on the F-7(0)-> D-5(3) Fano resonance lines were investigated. BaFCl:Sm2+ system showed a "normal" F-7(0)-> D-5(3) transition at 4K in spite of similar crystal structure and absorption profile with other MFX hosts. New Fano resonances were observed in the absorption spectra at higher energies (23,000-25,000 cm(-1)) for all MFX:Sm2+ systems at 4 K which persist up to room temperature. Preliminary energy level calculation showed that these resonance lines involve the interaction between higher excited L-5(J) states of 4f(6) configuration and 4f(5)5d(1) configuration. (C) 2015 Elsevier B.V. All rights reserved.
收录类别SCI ; EI
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/55371
专题中科院长春光机所知识产出
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Pal, P.,H. Hagemann,H. Bill and J. H. Zhang. Temperature and host dependence of the transition interference between f-f and f-d transitions of Sm2+ in matlockites[J]. Journal of Luminescence,2015,161:323-329.
APA Pal, P.,H. Hagemann,&H. Bill and J. H. Zhang.(2015).Temperature and host dependence of the transition interference between f-f and f-d transitions of Sm2+ in matlockites.Journal of Luminescence,161,323-329.
MLA Pal, P.,et al."Temperature and host dependence of the transition interference between f-f and f-d transitions of Sm2+ in matlockites".Journal of Luminescence 161(2015):323-329.
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