Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids | |
Xiao X.; Yan L. S.; Mei Z. M.; Zhu D. S.; Xu L.![]() | |
2014 | |
发表期刊 | Rsc Advances
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ISSN | ISBN/2046-2069 |
卷号 | 4期号:6页码:3096-3101 |
摘要 | Two novel macrocyclic organotin(IV) carboxylates [(n-Bu2Sn)L-1](2)center dot C7H8 (1) (L-1 = 2-(4-carboxyphenylcarbamoyl) benzoic acid) and [(n-Bu2Sn)L-2](3)center dot H2O (2) (L-2 = 5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)isophthalic acid) were generated by the reactions of dibutyltin oxide with amide dicarboxylic acids and characterized by elemental analysis, IR, H-1 and C-13 NMR spectroscopy. X-ray crystallography diffraction analyses reveal that 1 is a di-nuclear dicarboxylate ring and 2 is a trinuclear tricarboxylate macrocycle. With the help of intermolecular interactions, 1 and 2 construct supramolecular 3D architectures filled with cavities. Free toluene and water molecules are located in the cavities of 1 and 2 respectively as guests. Thermal analyses suggest that complex 2 is thermally more stable than 1. The antitumour activity of 1 and 2 has also been studied. |
收录类别 | SCI ; EI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/44492 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Xiao X.,Yan L. S.,Mei Z. M.,et al. Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids[J]. Rsc Advances,2014,4(6):3096-3101. |
APA | Xiao X.,Yan L. S.,Mei Z. M.,Zhu D. S.,&Xu L..(2014).Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids.Rsc Advances,4(6),3096-3101. |
MLA | Xiao X.,et al."Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids".Rsc Advances 4.6(2014):3096-3101. |
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