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Synthesis, characterization, and oxygen sensing properties of functionalized mesoporous silica SBA-15 and MCM-41 with a Pt(II)-porphyrin complex
Wang B. B.; Zhang L. M.; Li B.; Li Y.; Shi Y. H.; Shi T. S.
2014
发表期刊Sensors and Actuators B-Chemical
ISSNISBN/0925-4005
期号190页码:93-100
摘要A novel luminescent platinum(II) complex platinum 5,10,15,20-tetra{4-[(N-carbazyl)butyloxyphenyl]}porphyrin (PtTCBPyP) has been synthesized and characterized by H-1 NMR, elemental analysis, IR and UV-vis. The platinum porphyrin is assembled with mesoporous silica SBA-15 and MCM-41 resulting in the assembly materials PtTCBPyP/SBA-15 and PtTCBPyP/MCM-41. The luminescence of platinum porphyrin complex/silicate assemble materials can be quenched by molecular oxygen with very high response (I-0/I-100 > 8700 for PtTCBPyP/SBA-15(20 mg/g) and I-0/I-100 > 3800 for PtTCBPyP/MCM-41(20 mg/g)), indicating that platinum porphyrin complex/silicate systems can be employed to develop high performance oxygen sensors. Among this assembly system, PtTCBPyP/SBA-15(20 mg/g) exhibits the highest response of platinum porphyrin complex/silica. (C) 2013 Elsevier B.V. All rights reserved.
收录类别SCI ; EI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/44434
专题中科院长春光机所知识产出
推荐引用方式
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Wang B. B.,Zhang L. M.,Li B.,et al. Synthesis, characterization, and oxygen sensing properties of functionalized mesoporous silica SBA-15 and MCM-41 with a Pt(II)-porphyrin complex[J]. Sensors and Actuators B-Chemical,2014(190):93-100.
APA Wang B. B.,Zhang L. M.,Li B.,Li Y.,Shi Y. H.,&Shi T. S..(2014).Synthesis, characterization, and oxygen sensing properties of functionalized mesoporous silica SBA-15 and MCM-41 with a Pt(II)-porphyrin complex.Sensors and Actuators B-Chemical(190),93-100.
MLA Wang B. B.,et al."Synthesis, characterization, and oxygen sensing properties of functionalized mesoporous silica SBA-15 and MCM-41 with a Pt(II)-porphyrin complex".Sensors and Actuators B-Chemical .190(2014):93-100.
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