Reversible Switching of a Single-Dipole Molecule Imbedded in Two-Dimensional Hydrogen-Bonded Binary Molecular Networks

	Reversible Switching of a Single-Dipole Molecule Imbedded in Two-Dimensional Hydrogen-Bonded Binary Molecular Networks
	Zhang J. L.; Xu J. L.; Niu T. C.; Lu Y. H.; Liu L.; Chen W.
	2014
发表期刊	Journal of Physical Chemistry C
ISSN	ISBN/1932-7447
卷号	118 期号:3 页码:1712-1718
摘要	Understanding the single-molecule switching mechanism in densely packed, rationally designed, and highly organized nanostructures is crucial for practical applications such as high-density data storage devices. In this article, we report an in situ low-temperature scanning tunneling microscopy (LT-STM) investigation of reversible switching of a single-dipole molecule (chloroaluminium phthalocyanine, ClAlPc) imbedded in two-dimensional (2D) hydrogen-bonded binary molecular networks on graphite. The single-molecule switching is highly localized and reversible and leaves the neighboring molecular network unaffected. The switching direction can be controlled by the polarity of the voltage pulse applied to the STM tip. On the basis of experimental results and theoretical calculations, the reversible switching is proposed to be caused by the "shuttling" of the CI atom between two sides of the ClAlPc molecular plane.
收录类别	SCI ; EI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/44354
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Zhang J. L.,Xu J. L.,Niu T. C.,et al. Reversible Switching of a Single-Dipole Molecule Imbedded in Two-Dimensional Hydrogen-Bonded Binary Molecular Networks[J]. Journal of Physical Chemistry C,2014,118(3):1712-1718.
APA	Zhang J. L.,Xu J. L.,Niu T. C.,Lu Y. H.,Liu L.,&Chen W..(2014).Reversible Switching of a Single-Dipole Molecule Imbedded in Two-Dimensional Hydrogen-Bonded Binary Molecular Networks.Journal of Physical Chemistry C,118(3),1712-1718.
MLA	Zhang J. L.,et al."Reversible Switching of a Single-Dipole Molecule Imbedded in Two-Dimensional Hydrogen-Bonded Binary Molecular Networks".Journal of Physical Chemistry C 118.3(2014):1712-1718.

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