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Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor
Li J.; Zhang J. H.; Zhang X.; Hao Z. D.; Luo Y. S.
2014
发表期刊Journal of Alloys and Compounds
ISSNISBN/0925-8388
期号583页码:96-99
摘要An efficient near infrared (NIR) quantum cutting in CaSc2O4: Tm3+/Yb3+ phosphor has been demonstrated by the visible and NIR spectra properties as well as the decay curves of Tm3+: (1)G(4) level. Upon excitation of Tm3+: (1)G(4) level with a blue photon at 466 nm, Yb3+: F-2(5/2) level can emit two NIR photons around 1000 nm through cooperative energy transfer (ET) from Tm3+ to Yb3+ with the maximum energy transfer efficiency is 71%, and highest theoretical quantum efficiency reaches 171%, close to the limit of 200%. Because the energy of Yb3+ transition is matched well with band gap of crystalline silicon, the excellent downconversion luminescence property indicates that CaSc2O4: Tm3+/Yb3+ is a promising oxide material for increasing the conversion efficiency of crystalline silicon solar cells. (C) 2013 Elsevier Ltd. All rights reserved.
收录类别SCI ; EI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/43810
专题中科院长春光机所知识产出
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Li J.,Zhang J. H.,Zhang X.,et al. Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor[J]. Journal of Alloys and Compounds,2014(583):96-99.
APA Li J.,Zhang J. H.,Zhang X.,Hao Z. D.,&Luo Y. S..(2014).Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor.Journal of Alloys and Compounds(583),96-99.
MLA Li J.,et al."Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor".Journal of Alloys and Compounds .583(2014):96-99.
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