A series of inorganic aggregates composed of [MnV13O 38]7- polyoxoanions and transition metal cations

	A series of inorganic aggregates composed of [MnV13O 38]7- polyoxoanions and transition metal cations
	Lan Q.; Tan H.; Liu D.; Wang E.
	2013
发表期刊	Journal of Solid State Chemistry
ISSN	ISBN/00224596
期号	199
摘要	In this paper, three new extended solid frameworks based on polyoxoanion [MnV13O38]7-: K0.5Na 2.5Co2[MnV13O38]22H 2O (1), K1.5Na1.5Mn2[MnV 13O38] 22H2O (2) and K0.5Na 2.5Ni2[MnV13O38] 22H2O (3) have been synthesized and characterized by elemental analysis, IR spectrum, UV-Vis spectrum, thermal gravimetric analysis, magnetism, electrochemical analyses and single crystal X-ray diffraction. The structure analyses reveal that the polyoxoanions in compounds 1-3 are isostructural, which can be described as two transition metal-supported {M2(H2O) 10(MnV13O38)} (M=Co2+, Mn 2+ and Ni2+) units connected by a K+. And then the polyoxoanions are stacked by the electrostatic interactions with other K+ and Na+ cation to form a 2D layer. The variable-temperature magnetic susceptibility of compound 1 has been studied as the example, which shows an antiferromagnetic interaction. 2012 Elsevier Inc. All rights reserved.
收录类别	SCI ; EI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/40845
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Lan Q.,Tan H.,Liu D.,et al. A series of inorganic aggregates composed of [MnV13O 38]7- polyoxoanions and transition metal cations[J]. Journal of Solid State Chemistry,2013(199).
APA	Lan Q.,Tan H.,Liu D.,&Wang E..(2013).A series of inorganic aggregates composed of [MnV13O 38]7- polyoxoanions and transition metal cations.Journal of Solid State Chemistry(199).
MLA	Lan Q.,et al."A series of inorganic aggregates composed of [MnV13O 38]7- polyoxoanions and transition metal cations".Journal of Solid State Chemistry .199(2013).

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