Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer

	Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer
	Jin F.; Chu B.; Li W.; Su Z.; Zhao B.; Yan X.; Zhang F.; Fan D.; Zhang T.; Gao Y.; Lee C. S.; Wang J.
	2013
发表期刊	Solar Energy Materials and Solar Cells
ISSN	ISBN/09270248
期号	117
摘要	We demonstrate response and lifetime improvements for organic photovoltaic (OPV) by using organic bathophenanthroline (Bphen) and inorganic molybdenum oxide (MoO3) as a compound cathode buffer layer (CBL). Not only power conversion efficiency (PCE) increases by 27% but also working and storage lifetimes extend at least 10 and 60 times respectively comparing with PV cell with 5 nm thick Bphen as CBL. The optimized PV structure is ITO/CuPc (20 nm)/C60 (40 nm)/Bphen (2 nm)/MoO3 (5 nm)/Al and the CBL of the reference device is 5 nm Bphen without MoO3 layer. The achievement of PV performance and lifetime improvement by introducing such a compound CBL is attributed to appropriate level alignment between C 60, Bphen and MoO3, and stable inorganic MoO3 can prevent from superior oxygen and moisture diffusion into the C60 acceptor layer. The detailed working mechanism of the compound Bphen/MoO 3 CBL in the OPV cells is also argued. 2013 Elsevier B.V.
收录类别	SCI ; EI
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/40709
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Jin F.,Chu B.,Li W.,et al. Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer[J]. Solar Energy Materials and Solar Cells,2013(117).
APA	Jin F..,Chu B..,Li W..,Su Z..,Zhao B..,...&Wang J..(2013).Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer.Solar Energy Materials and Solar Cells(117).
MLA	Jin F.,et al."Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer".Solar Energy Materials and Solar Cells .117(2013).

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Jin-2013-Improvement（629KB）			开放获取	CC BY-NC-ND	浏览请求全文