Changchun Institute of Optics,Fine Mechanics and Physics,CAS
High pressure synthesis and characterization of noble metal nitride IrNx | |
Ding Z.; Qiu L.; Li Y.; Zheng D.; Yao B.; Liu L.; Zheng W.; Liu X. | |
2013 | |
发表期刊 | Materials Letters |
ISSN | ISBN/0167577X |
期号 | 107 |
摘要 | Novel iridium nitrides (IrNx) have been synthesized from a double decomposition reaction between IrCl3 and Li3N powders under high pressure (5 GPa) and high temperature (1273 K) conditions. X-ray diffraction and Raman spectra analysis reveals that the as-synthesized IrNx have a cubic crystal structure. The lattice constants of IrNx are 4.06 A. The x-ray photoelectron spectrum indicates the N content (x) in IrNx is 0.3. The first-principles calculations further suggest that iridium nitride is face-centered cubic structure, which has not ever been reported experimentally. Such structure is mechanical stable even under 10 GPa and 1273 K conditions. 2013 Elsevier B.V. |
收录类别 | SCI ; EI |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/40687 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Ding Z.,Qiu L.,Li Y.,et al. High pressure synthesis and characterization of noble metal nitride IrNx[J]. Materials Letters,2013(107). |
APA | Ding Z..,Qiu L..,Li Y..,Zheng D..,Yao B..,...&Liu X..(2013).High pressure synthesis and characterization of noble metal nitride IrNx.Materials Letters(107). |
MLA | Ding Z.,et al."High pressure synthesis and characterization of noble metal nitride IrNx".Materials Letters .107(2013). |
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