The wurtzite-type ZnS:Cu2+Mn2+ nanowires (NWs) were prepared by a simple hydrothermal method at 180 degrees C without any surface-active agent. The results of XRD, EDAX and XPS showed that both the Cu2+ and Mn2+ ions were incorporated into the ZnS lattice. The maximum concentration of the Cu2+ ions in the ZnS and Zn0.99Mn0.01S NWs was 7% and 1%, respectively. The maximum concentration of the Mn2+ ions in the Zn0.99Mn0.01S NWs can reach to 10%. The ZnS:Cu2+ NWs exhibited the Cu2+-related emission peak centered at 540 nm coming from sulfur vacancy to t(2) level of Cu2+, while the ZnS:Cu2+Mn2+ NWs exhibited the Mn2+ (T-4(1)-(6)A(1)) and Cu2+ (interstitial S to t(2) level of Cu2+) related transition centered at 577 nm and 501 nm, respectively. Moreover, the ZnS:Cu2+Mn2+ NWs showed the room temperature ferromagnetism property, and the saturation magnetization was increased as the Mn2+ doped ratio increased. (C) 2013 Elsevier B.V. All rights reserved.
Yang J. H.,Wang B. J.,Cao J.,et al. Controllable photoluminescent-magnetic dual-encoded wurtzite ZnS:Cu2+Mn2+ nanowires modulated by Cu2+ and Mn2+ ions[J]. Journal of Alloys and Compounds,2013,574.
APA
Yang J. H..,Wang B. J..,Cao J..,Han D. L..,Feng B..,...&Wang T. T..(2013).Controllable photoluminescent-magnetic dual-encoded wurtzite ZnS:Cu2+Mn2+ nanowires modulated by Cu2+ and Mn2+ ions.Journal of Alloys and Compounds,574.
MLA
Yang J. H.,et al."Controllable photoluminescent-magnetic dual-encoded wurtzite ZnS:Cu2+Mn2+ nanowires modulated by Cu2+ and Mn2+ ions".Journal of Alloys and Compounds 574(2013).
修改评论