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Improved luminescence properties of europium complexes encapsulated into mesoporous SBA-15
Li S. W.; Song H. W.; Li W. L.; Lu S. Z.; Ren X. G.
2008
发表期刊Journal of Nanoscience and Nanotechnology
ISSN1533-4880
卷号8期号:3页码:1272-1278
摘要Two kinds of Eu(3+) complexes-Eu(TTA)(3)(TPPO)(2) (TTA: thenoyltrifluoroacetone, TPPO: triphenylphosphineoxide) and Eu(BA)(3)(TPPO)(2) (BA: 1-benzoylacetone)-were fully encapsulated, uniformly distributed into the channels of unmodified and modified SBA-15, and structurally characterized. The luminescent properties of the encapsulated complexes were systematically studied in contrast to the pure complexes. The results indicate that the excitation bands assigned to the pi-pi* electron transition of the ligands for Eu(3+) complexes encapsulated in SBA-15 were split into different components, and the (5)D(0)-(7)F(0) transitions became partly allowed. The emission lines for the (5)D(0)-(7)F(2) transitions became broader and the relative intensity for different crystal field components varied greatly in comparison to the pure complex. Most importantly, the photostability and thermostability of the emissions improved considerably.
收录类别SCI ; EI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/34500
专题中科院长春光机所知识产出
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Li S. W.,Song H. W.,Li W. L.,et al. Improved luminescence properties of europium complexes encapsulated into mesoporous SBA-15[J]. Journal of Nanoscience and Nanotechnology,2008,8(3):1272-1278.
APA Li S. W.,Song H. W.,Li W. L.,Lu S. Z.,&Ren X. G..(2008).Improved luminescence properties of europium complexes encapsulated into mesoporous SBA-15.Journal of Nanoscience and Nanotechnology,8(3),1272-1278.
MLA Li S. W.,et al."Improved luminescence properties of europium complexes encapsulated into mesoporous SBA-15".Journal of Nanoscience and Nanotechnology 8.3(2008):1272-1278.
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