Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Electroluminescence from singlet excited-state of the exciplex between (2,3-Dicarbonitrilopyrazino 2,3-f 1,10 phenanthroline)Re(CO)(3)Cl and CBP | |
其他题名 | 论文其他题名 |
Si Z. J.; Li J.; Li B.; Hong Z. R.; Liu S. Y.; Li W. L. | |
2008 | |
发表期刊 | Journal of Physical Chemistry C |
ISSN | 1932-7447 |
卷号 | 112期号:10页码:3920-3925 |
摘要 | (2,3-Dicarbonitrilopyrazino[2,3-f] [1,10]phenanthroline)Re(CO)(3)Cl (Dicnpp-Re) is synthesized successfully, and the photophysics, the electrochemistry, and the thermogravimetric analysis are performed to study the properties of Dicnpp-Re. It is found that the exciplex with lambda(max) at similar to 620 nm can be formed between CBP and Dicnpp-Re, and the exciplex emission is confirmed to be from the singlet excited state of the bound CBP and Dicnpp-Re molecules by the measurement of the lifetime of the CBP/Dicnpp-Re film. Color-tunable EL devices based on a host material of CBP and a dopant material of Dicnpp-Re are fabricated. A CBP/Dicnpp-Re (3%) based EL device emits white light with CIE coordinates of (x = 0.35, y = 0.32). The spectrum consists of three discrete bands centered at 380 nm from CBP, 560 nm from the characteristic (MLCT)-M-3 state of Dicnpp-Re, and 620 nm from the exciplex between Dicnpp-Re and CBP. When the doping concentration is 16%, the EL spectrum mainly demonstrates the red exciplex emission with CIE coordinates of (x = 0.57, y = 0.33). |
收录类别 | SCI ; EI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/26516 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Si Z. J.,Li J.,Li B.,et al. Electroluminescence from singlet excited-state of the exciplex between (2,3-Dicarbonitrilopyrazino 2,3-f 1,10 phenanthroline)Re(CO)(3)Cl and CBP[J]. Journal of Physical Chemistry C,2008,112(10):3920-3925. |
APA | Si Z. J.,Li J.,Li B.,Hong Z. R.,Liu S. Y.,&Li W. L..(2008).Electroluminescence from singlet excited-state of the exciplex between (2,3-Dicarbonitrilopyrazino 2,3-f 1,10 phenanthroline)Re(CO)(3)Cl and CBP.Journal of Physical Chemistry C,112(10),3920-3925. |
MLA | Si Z. J.,et al."Electroluminescence from singlet excited-state of the exciplex between (2,3-Dicarbonitrilopyrazino 2,3-f 1,10 phenanthroline)Re(CO)(3)Cl and CBP".Journal of Physical Chemistry C 112.10(2008):3920-3925. |
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