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Preparation, photo- and electro-luminescent properties of a novel complex of Tb (III) with a tripod ligand
其他题名论文其他题名
Yu T. Z.; Zhao W.; Fan D. W.; Hong Z. R.; Su W. M.
2008
发表期刊Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
ISSN1386-1425
卷号69期号:2页码:654-658
摘要A novel Tb(III) complex TbL (L=tris[2-(2-carboxyphenoxy)ethyl]amine, H3L) was synthesized and characterized by means of elemental analyses, IR spectra, thermal analyses, and molar conductivity measurement. The photoluminescent properties of the complex were investigated. In addition, PVK doping Tb(III) complex was fabricated as the emissive layer by spin-coating and its electroluminescent properties were studied, in which the structure of the device was ITO (indium tin oxide)/PVK (polyvinylcarbazole)/PVK: TbL/PBD (2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole)/LiF/Al. It was indicated that pure green and narrow bandwidth emission at 545 nm from photoluminescence of TbL complex film and the organic electroluminescent device is the characteristic emission of Tb(III) ion, and the electroluminescence spectrum of the device was very similar to that of the photoluminescence of TbL complex film. The lowest triplet level of the ligand was calculated from the phosphorescence spectrum of GdL in N,N-dimethyl formamide (DMF) dilute solution determined at 77 K, and the energy transfer mechanisms in TbL complex were discussed. (c) 2007 Elsevier B.V. All rights reserved.
收录类别SCI ; EI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/26503
专题中科院长春光机所知识产出
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Yu T. Z.,Zhao W.,Fan D. W.,et al. Preparation, photo- and electro-luminescent properties of a novel complex of Tb (III) with a tripod ligand[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2008,69(2):654-658.
APA Yu T. Z.,Zhao W.,Fan D. W.,Hong Z. R.,&Su W. M..(2008).Preparation, photo- and electro-luminescent properties of a novel complex of Tb (III) with a tripod ligand.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,69(2),654-658.
MLA Yu T. Z.,et al."Preparation, photo- and electro-luminescent properties of a novel complex of Tb (III) with a tripod ligand".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 69.2(2008):654-658.
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