Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Oxygen-sensing materials based on Ru(bpy)(3) (2+) covalently grafted MSU-3 mesoporous molecular sieves | |
其他题名 | 论文其他题名 |
Zhang H. R.; Li B.; Lei B. F.; Li W. L. | |
2008 | |
发表期刊 | Journal of Luminescence |
ISSN | 0022-2313 |
卷号 | 128期号:8页码:1331-1338 |
摘要 | Novel oxygen-sensing materials consisting of [Ru(bpy)(2)(Bpy-Si)](2+) portions covalently grafted onto the backbone of MSU-3 mesostructured silica-based network were prepared in a two-step process with the help of P123 surfactant. The 2,2'-bipyridyl covalently grafted with 3-aminopropyltriethoxysilane was used not only as sol-gel precursor but also as the second ligand of the Ru(bpy)(2)Cl-2 center dot 2H2O complex for the preparation of sol-gel-derived silicates for oxygen-sensing materials. The downward oxygen-sensing Stern-Volmer plots can be attributed to the heterogeneous environment of the luminophore within the MSU-3. silica. The MSU-3 sample obtained at 10 degrees C showed better oxygen-sensing performance due to its special morphology. (c) 2008 Published by Elsevier B.V. |
收录类别 | SCI ; EI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/26431 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Zhang H. R.,Li B.,Lei B. F.,et al. Oxygen-sensing materials based on Ru(bpy)(3) (2+) covalently grafted MSU-3 mesoporous molecular sieves[J]. Journal of Luminescence,2008,128(8):1331-1338. |
APA | Zhang H. R.,Li B.,Lei B. F.,&Li W. L..(2008).Oxygen-sensing materials based on Ru(bpy)(3) (2+) covalently grafted MSU-3 mesoporous molecular sieves.Journal of Luminescence,128(8),1331-1338. |
MLA | Zhang H. R.,et al."Oxygen-sensing materials based on Ru(bpy)(3) (2+) covalently grafted MSU-3 mesoporous molecular sieves".Journal of Luminescence 128.8(2008):1331-1338. |
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