The preparation and oxygen sensing properties of optical materials based on two trinuclear starburst ruthenium(II) complexes: [Ru-3(bpy)(6)(TMMB)](6+) (1) and [Ru-3(phen)(6)(TMMB)](6+) (2) (bpy = 2,2'-bpyridine, phen = 1, 10-phenathroline, TMMB = 1,3,5-tris [2-(2'-pyridyl)benzimidazoyl]methylbenzene) assembled in two mesoporous silicate (MS) are described in this paper. The luminescence of Ru complexes/silicate assemble materials can be quenched by molecular oxygen with good sensitivity (I-0/I-1 > 5 for 2/MS and I-0/I-1 > 3 for 1/MS), indicating that trinuclear starburst Ru(II) complexes/MS systems are sensitive to oxygen molecules. (C) 2007 Elsevier B.V. All rights reserved.
Wang B.,Liu Y.,Li B.,et al. Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica[J]. Journal of Luminescence,2008,128(3):341-347.
APA
Wang B.,Liu Y.,Li B.,Yue S.,&Li W..(2008).Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica.Journal of Luminescence,128(3),341-347.
MLA
Wang B.,et al."Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica".Journal of Luminescence 128.3(2008):341-347.
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