Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Highly efficient electrophosphorescence devices based on iridium complexes with high efficiency over a wide range of current densities | |
其他题名 | 论文其他题名 |
Zhang L. Y.; Chen P.; Li B.; Hong Z. R.; Liu S. Y. | |
2008 | |
发表期刊 | Journal of Physics D-Applied Physics |
ISSN | 0022-3727 |
卷号 | 41期号:24 |
摘要 | Three new luminescent cyclometalated iridium (III) complexes are successfully synthesized. The cyclometalated ligand used here is 2-(2-fluorophenyl)-benzothiazole (F-BT). The auxiliary ligands are acetylacetone (acac), 1,1,1-trifluoroacetylaceton (3F-acac), 1,1,1,5,5,5-hexafluoroacetylacetone (6F-acac), respectively. All complexes exhibit bright photoluminescence at room temperature. Organic light-emitting diodes are fabricated by doping the iridium (III) complexes in 4, 4'-N, N'-dicarbazole-biphenyl (CBP), and the device characteristics are investigated. Among these devices, the performances of the optimized devices based on 1 at high current density are among the best reported for devices with iridium (III) complexes as emitters. EL efficiencies show weak dependence on doping concentration and current density. The optimized device exhibits a peak current efficiency of 28.5 cd A(-1) and a power efficiency of 11.2 lm W(-1), respectively, at 20 mA cm(-2), an efficiency of 22.7 cd A(-1) at 100 mA cm(-2), 80% of the maximum, can be achieved. Short triplet decay time of 1 measured in solid films is supposed to be responsible for the minor loss in EL efficiency, which suggests depressed triplet-triplet annihilation and site saturation of the phosphor. Efficient exciton formation on the molecules of 1 by direct charge trapping and confinement within the emissive layer also make for outstanding electrophosphorescent performances. |
收录类别 | SCI ; EI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/26391 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Zhang L. Y.,Chen P.,Li B.,et al. Highly efficient electrophosphorescence devices based on iridium complexes with high efficiency over a wide range of current densities[J]. Journal of Physics D-Applied Physics,2008,41(24). |
APA | Zhang L. Y.,Chen P.,Li B.,Hong Z. R.,&Liu S. Y..(2008).Highly efficient electrophosphorescence devices based on iridium complexes with high efficiency over a wide range of current densities.Journal of Physics D-Applied Physics,41(24). |
MLA | Zhang L. Y.,et al."Highly efficient electrophosphorescence devices based on iridium complexes with high efficiency over a wide range of current densities".Journal of Physics D-Applied Physics 41.24(2008). |
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